Reagents have been synthesised that behave as both Lewis acids and nucleophiles. Reaction of these reagents with electrophiles has led to the finding that diastereoselectivity is observed upon addition to aldehydes. An ordered transition state to account for the observed stereochemistry is proposed herei
The stereochemical course of the aldol reaction has been studied with rationally designed and synthe...
The basis for diastereoselectivity in Lewis-acid-catalyzed Mukaiyama aldol reactions was studied usi...
418 p.Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2008.A catalytic system involving ...
A conventional approach in the construction of complex molecules is to use existing substrate stereo...
During investigations of cyclization reactions between chiral allylsilanes and N-acyliminium ions, i...
ABSTRACT: Alkenes have been discovered to be chelating groups to Zn(II), enforcing highly stereosele...
Intramolecular isomerization in pentacoordinate compounds can play an essential role for the adjustm...
A conventional approach in the construction of complex molecules is to use existing substrate stereo...
Compounds with stereogenic silicon that are chiral can be used in organic synthesis as chiral reagen...
(Z)-Vinyl iodides 6a\u2013d were synthesized in high yield with good diastereo- and enantioselectivi...
A survey is made of the literature concerning the resolution of asymmetric organosilicon compounds a...
Alkenes have been discovered to be chelating groups to Zn(II), enforcing highly stereoselective add...
Investigations into factors which influence the transition state geometry of the aldol reaction are ...
The Felkin–Anh model has been widely accepted to describe stereochemical outcomes in nucleophilic ad...
The role of the solvent, the organometallic reagent, and the nature of the substrate for the diaster...
The stereochemical course of the aldol reaction has been studied with rationally designed and synthe...
The basis for diastereoselectivity in Lewis-acid-catalyzed Mukaiyama aldol reactions was studied usi...
418 p.Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2008.A catalytic system involving ...
A conventional approach in the construction of complex molecules is to use existing substrate stereo...
During investigations of cyclization reactions between chiral allylsilanes and N-acyliminium ions, i...
ABSTRACT: Alkenes have been discovered to be chelating groups to Zn(II), enforcing highly stereosele...
Intramolecular isomerization in pentacoordinate compounds can play an essential role for the adjustm...
A conventional approach in the construction of complex molecules is to use existing substrate stereo...
Compounds with stereogenic silicon that are chiral can be used in organic synthesis as chiral reagen...
(Z)-Vinyl iodides 6a\u2013d were synthesized in high yield with good diastereo- and enantioselectivi...
A survey is made of the literature concerning the resolution of asymmetric organosilicon compounds a...
Alkenes have been discovered to be chelating groups to Zn(II), enforcing highly stereoselective add...
Investigations into factors which influence the transition state geometry of the aldol reaction are ...
The Felkin–Anh model has been widely accepted to describe stereochemical outcomes in nucleophilic ad...
The role of the solvent, the organometallic reagent, and the nature of the substrate for the diaster...
The stereochemical course of the aldol reaction has been studied with rationally designed and synthe...
The basis for diastereoselectivity in Lewis-acid-catalyzed Mukaiyama aldol reactions was studied usi...
418 p.Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2008.A catalytic system involving ...
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