2-Fluoro-N-o-tolylbenzamide

  • Aamer Saeed
  • Rasheed Ahmad Khera
  • Shahid Ameen
  • Jim Simpson
  • Roderick G. Stanley
Publication date
January 2009
Publisher
International Union of Crystallography (IUCr)
Journal
Acta Crystallographica Section E Structure Reports Online

Abstract

In the title compound, C14H12FNO, the ortho-F atom and corresponding H atom on the fluorobenzene ring are disordered over two positions with occupancies of 0.856 (4) and 0.144 (4). The amide unit is planar with a maximum deviation of 0.0057 (16) Å and the amide plane makes dihedral angles of 38.27 (11)° with the fluorobenzene ring plane and 37.53 (10)° with the tolyl ring. The two benzene rings are inclined at an angle of 4.17 (15)°. In the crystal structure, chains form along b through N—H...O hydrogen bonds augmented by C—H...π interactions. Additional intermolecular C—H...O and C—H...F hydrogen bonds further stabilize the structure, forming layers ...

Extracted data

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