&#956;-4,4&#8242;-Bipyridine-bis[aqua(4-hydroxypyridine-2,6-dicarboxylato)copper(II)]

Mei-Li Zhang
Hua-Li Cui
Lou-Jun Gao
Xiao-Li Chen
Ya-Li Qiao

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Publication date

March 2012

DOI

10.1107/S1600536812004758

Publisher

International Union of Crystallography (IUCr)

Journal

Acta Crystallographica Section E Structure Reports Online

Abstract

The title compound, [Cu2(C7H3NO5)2(C10H8N2)(H2O)2], exhibits a centrosymmetric binuclear molecule. Each completely deprotonated 4-hydroxypyridine-2,6-dicarboxylic acid molecule assumes a tridentate chelating coordination mode. The square-pyramidal coordination geometry around the CuII ion is completed by the bridging bipyridine ligand and an apical water molecule. Adjacent complexes are connected via O&#8212;H...O and C&#8212;H...O hydrogen bonds to generate a three-dimensional supramolecular structure

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&#956;-4,4&#8242;-Bipyridine-bis[aqua(4-hydroxypyridine-2,6-dicarboxylato)copper(II)]

Abstract

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&#956;-4,4&#8242;-Bipyridine-bis[aqua(4-hydroxypyridine-2,6-dicarboxylato)copper(II)]

Abstract

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&amp;#956;-4,4&amp;#8242;-Bipyridine-bis[aqua(4-hydroxypyridine-2,6-dicarboxylato)copper(II)]

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μ-4,4′-Bipyridine-bis[aqua(4-hydroxypyridine-2,6-dicarboxylato)copper(II)]

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