The adsorption of tetrahydroxyquinone (THQ) on the Cu(111) surface at different temperatures gives rise to different ordered structures, unveiled by density functional theory (DFT) modelling of scanning tunnelling microscopy (STM) topography and by X-ray absorption spectroscopy (XAS) measurements. After annealing, the THQ films generated tetrameric Cu clusters embedded in a metal–organic tetraoxyquinone (TOQ) network, whose electronic properties were thoroughly studied. The remarkable agreement between the STM results and periodic calculations was exploited to model C and O K-edge XA spectra recorded before (room temperature, RT) and after annealing (high temperature, HT). The subsequent analysis of the C and O TOQ@Cu(111) K-edge XA spectra...
A novel approach of identifying metal atoms within a metal–organic surface coordination network usin...
Benzotriazole (BTAH) has been used for several industrial applications, but most commonly as a corro...
The oligothiophene molecule family has a tunable energy gap between the highest occupied and lowest ...
The progress of modern technology is dominated by shrinking component size (with a goal of reaching ...
The adsorption of trimesic acid (TMA) on Cu(110) has been studied in the temperature range between 1...
The adsorption of trimesic acid (TMA) on Cu(110) has been studied in the temperature range between 1...
International audienceWe have investigated the role played by the atomic structure and reactivity of...
We report on the assembly of a highly ordered array of copper tetrameric clusters, coordinated into ...
The local structure of the methoxy species on Cu(110) has been investigated experimentally using che...
A novel approach of identifying metal atoms within a metal-organic surface coordination network usin...
The formation of hydroxyl chains from water dissociation on the Cu(110) surface has been studied by ...
We performed first-principles calculations within the density functional theory aimed to investigate...
Funding: UK Engineering and Physical Sciences Research Council (EPSRC), Grant Number(s) EP/M506631/1...
A novel approach of identifying metal atoms within a metal–organic surface coordination network usin...
Benzotriazole (BTAH) has been used for several industrial applications, but most commonly as a corro...
The oligothiophene molecule family has a tunable energy gap between the highest occupied and lowest ...
The progress of modern technology is dominated by shrinking component size (with a goal of reaching ...
The adsorption of trimesic acid (TMA) on Cu(110) has been studied in the temperature range between 1...
The adsorption of trimesic acid (TMA) on Cu(110) has been studied in the temperature range between 1...
International audienceWe have investigated the role played by the atomic structure and reactivity of...
We report on the assembly of a highly ordered array of copper tetrameric clusters, coordinated into ...
The local structure of the methoxy species on Cu(110) has been investigated experimentally using che...
A novel approach of identifying metal atoms within a metal-organic surface coordination network usin...
The formation of hydroxyl chains from water dissociation on the Cu(110) surface has been studied by ...
We performed first-principles calculations within the density functional theory aimed to investigate...
Funding: UK Engineering and Physical Sciences Research Council (EPSRC), Grant Number(s) EP/M506631/1...
A novel approach of identifying metal atoms within a metal–organic surface coordination network usin...
Benzotriazole (BTAH) has been used for several industrial applications, but most commonly as a corro...
The oligothiophene molecule family has a tunable energy gap between the highest occupied and lowest ...