Add to ORKGCyclopropenylmethyl sulfonamides with tethered heteroaromatics have been demonstrated to undergo divergent gold-catalysed cyclisation reactions. A formal dearomative (4+3) cycloaddition takes place with furan-tethered substrates, yielding densely functionalised 5,7-fused heterocycles related to the bioactive curcusone natural products. Indole-tethered substrates display divergent reactivity giving biologically important tetrahydro-β-carbolines via a Friedel-Crafts mechanism
[4+2] cyclization/cycloaddition reactions are among the most useful transformations in synthetic org...
Synthetic organic chemistry has been markedly affected by the booming of gold catalysis over the pas...
MasterThe catalysis of organic reactions mediated by transition metals has become an essential tool ...
Cyclopropenes are unsaturated, three-membered ring systems that are highly strained and as a result,...
Over the years, gold catalysis has materialized as an incredible synthetic approach among the scient...
The reaction of indoles and stabilized cyclopropyl alkynes under gold- and/or gold & Brønsted acid-c...
The stereospecific gold(I)-catalyzed nucleophilic cyclization of β-monosubstituted o-(alkynyl)styren...
The use of ring-fused gem-dihalocyclopropanes, Au(I)-catalyzed cyclization reactions, and chemoenzym...
The reaction of alkenyldiazo compounds with styrene derivatives in the presence of [Au(IPr)(MeCN)][S...
Gold π-catalysis has been used to overcome many challenges in synthesis, either by achieving complex...
The last decade has witnessed dramatic growth in the number of reactions catalyzed by gold complexes...
The work in this thesis was undertaken in Chemistry and Biological Chemistry, School of Physical and...
This thesis describes the research carried out in the development of novel homogeneous gold(I)-catal...
A diastereoselective, gold-catalyzed cascading cycloisomerization of alkylidene cyclopropane bearing...
An unprecedented gold-catalyzed diastereoselective cycloisomerization of 1,6-diynes bearing an alkyl...
[4+2] cyclization/cycloaddition reactions are among the most useful transformations in synthetic org...
Synthetic organic chemistry has been markedly affected by the booming of gold catalysis over the pas...
MasterThe catalysis of organic reactions mediated by transition metals has become an essential tool ...
Cyclopropenes are unsaturated, three-membered ring systems that are highly strained and as a result,...
Over the years, gold catalysis has materialized as an incredible synthetic approach among the scient...
The reaction of indoles and stabilized cyclopropyl alkynes under gold- and/or gold & Brønsted acid-c...
The stereospecific gold(I)-catalyzed nucleophilic cyclization of β-monosubstituted o-(alkynyl)styren...
The use of ring-fused gem-dihalocyclopropanes, Au(I)-catalyzed cyclization reactions, and chemoenzym...
The reaction of alkenyldiazo compounds with styrene derivatives in the presence of [Au(IPr)(MeCN)][S...
Gold π-catalysis has been used to overcome many challenges in synthesis, either by achieving complex...
The last decade has witnessed dramatic growth in the number of reactions catalyzed by gold complexes...
The work in this thesis was undertaken in Chemistry and Biological Chemistry, School of Physical and...
This thesis describes the research carried out in the development of novel homogeneous gold(I)-catal...
A diastereoselective, gold-catalyzed cascading cycloisomerization of alkylidene cyclopropane bearing...
An unprecedented gold-catalyzed diastereoselective cycloisomerization of 1,6-diynes bearing an alkyl...
[4+2] cyclization/cycloaddition reactions are among the most useful transformations in synthetic org...
Synthetic organic chemistry has been markedly affected by the booming of gold catalysis over the pas...
MasterThe catalysis of organic reactions mediated by transition metals has become an essential tool ...