Add to ORKGThe 16-membered lactone 17was synthesized and alkylated to yield a 4:1 ratio of 20 and 19 respectively. The product ratio was rationalized by molecular mechanics calculations on 18. A new polar map convention was developed for conformational analysis of cyclohexadecane.[See Thesis for Diagram]Science, Faculty ofChemistry, Department ofGraduat
1. On the basis of data obtained by the dipole moment method, cis-2-methyl (or phenyl)-4-methyl-1,3-...
This study aims to investigate the molecular structure and polymorphism of trans-1,4-cyclohexanedime...
Linearized embedding is a variant on the usual distance geometry methods for finding atomic Cartesia...
A number of 14-membered lactones, derived from 42 or 43 were used to investigate a series of alkylat...
The conformationally controlled reactions of macrolides 42, 43, 72 and 74 were investigated. Treatme...
11-(1,3-Dithian-2-yl)-13-tetradecanolide (71) was synthesized in a ten step sequence in approximatel...
As a part of a continuing study of the chemistry and conformational behaviour of macrocyclic β-keto...
Author Institution: Department of Chemistry, University of California; Department of Chemistry, Harv...
With the introduction of hydride reducing agents, organic chemists were able to search for an explan...
Spiro[cyclohexane-1,4′-[3,5]dioxabicyclo[5.1.0]octanes] were synthesized, and their conformational b...
Different projects are represented by individual chapters (Part I-III). Parts I and II present compl...
Author Institution: Department of Chemistry, University of Wisconsin“Cyclic ketones (I) with $n=5$ o...
The synthesis of 10,10-dimethyltridecanolide (42) was achieved via a fifteen-step sequence in 9% ove...
Enantioselective synthesis of a new family of unsaturated six-membered carbocyclic nucleosides using...
A convergent synthesis using dithiane alkylations to produce a long chain hydroxy acid, and subseque...
1. On the basis of data obtained by the dipole moment method, cis-2-methyl (or phenyl)-4-methyl-1,3-...
This study aims to investigate the molecular structure and polymorphism of trans-1,4-cyclohexanedime...
Linearized embedding is a variant on the usual distance geometry methods for finding atomic Cartesia...
A number of 14-membered lactones, derived from 42 or 43 were used to investigate a series of alkylat...
The conformationally controlled reactions of macrolides 42, 43, 72 and 74 were investigated. Treatme...
11-(1,3-Dithian-2-yl)-13-tetradecanolide (71) was synthesized in a ten step sequence in approximatel...
As a part of a continuing study of the chemistry and conformational behaviour of macrocyclic β-keto...
Author Institution: Department of Chemistry, University of California; Department of Chemistry, Harv...
With the introduction of hydride reducing agents, organic chemists were able to search for an explan...
Spiro[cyclohexane-1,4′-[3,5]dioxabicyclo[5.1.0]octanes] were synthesized, and their conformational b...
Different projects are represented by individual chapters (Part I-III). Parts I and II present compl...
Author Institution: Department of Chemistry, University of Wisconsin“Cyclic ketones (I) with $n=5$ o...
The synthesis of 10,10-dimethyltridecanolide (42) was achieved via a fifteen-step sequence in 9% ove...
Enantioselective synthesis of a new family of unsaturated six-membered carbocyclic nucleosides using...
A convergent synthesis using dithiane alkylations to produce a long chain hydroxy acid, and subseque...
1. On the basis of data obtained by the dipole moment method, cis-2-methyl (or phenyl)-4-methyl-1,3-...
This study aims to investigate the molecular structure and polymorphism of trans-1,4-cyclohexanedime...
Linearized embedding is a variant on the usual distance geometry methods for finding atomic Cartesia...