In sharp contrast with the standard [2 + 2 + 2] cycloaddition reaction of diyne/ene, cobalt-mediated cycloadditions with γ-alkylidenebutenolide led to unprecedented cobalt(III) polycyclic complexes. A plausible mechanism supported by a computational study based on an unusual fragmentation of the butenolide moiety was postulated to account for this original reaction
The first transannular [4 + 2] cycloaddition reactions of macrocyclic dicobalt hexacarbonyl–dienyne ...
The first transannular [4 + 2] cycloaddition reactions of macrocyclic dicobalt hexacarbonyl-dienyne ...
The first transannular [4 + 2] cycloaddition reactions of macrocyclic dicobalt hexacarbonyl-dienyne ...
In sharp contrast with the standard [2 + 2 + 2] cycloaddition reaction of diyne/ene, cobalt-mediated...
In sharp contrast with the standard [2 + 2 + 2] cycloaddition reaction of diyne/ene, cobalt-mediated...
In sharp contrast with the standard [2 + 2 + 2] cycloaddition reaction of diyne/ene, cobalt-mediated...
In sharp contrast with the standard [2 + 2 + 2] cycloaddition reaction of diyne/ene, cobalt-mediated...
International audienceIn sharp contrast with the standard [2 + 2 + 2] cycloaddition reaction of diyn...
International audienceIn sharp contrast with the standard [2 + 2 + 2] cycloaddition reaction of diyn...
International audienceIn sharp contrast with the standard [2 + 2 + 2] cycloaddition reaction of diyn...
International audienceIn sharp contrast with the standard [2 + 2 + 2] cycloaddition reaction of diyn...
International audienceIn sharp contrast with the standard [2 + 2 + 2] cycloaddition reaction of diyn...
The molecular complexity of recently reported cobalt(III) polycyclic complexes, resulting from an in...
The molecular complexity of recently reported cobalt(III) polycyclic complexes, resulting from an in...
The first transannular [4 + 2] cycloaddition reactions of macrocyclic dicobalt hexacarbonyl–dienyne ...
The first transannular [4 + 2] cycloaddition reactions of macrocyclic dicobalt hexacarbonyl–dienyne ...
The first transannular [4 + 2] cycloaddition reactions of macrocyclic dicobalt hexacarbonyl-dienyne ...
The first transannular [4 + 2] cycloaddition reactions of macrocyclic dicobalt hexacarbonyl-dienyne ...
In sharp contrast with the standard [2 + 2 + 2] cycloaddition reaction of diyne/ene, cobalt-mediated...
In sharp contrast with the standard [2 + 2 + 2] cycloaddition reaction of diyne/ene, cobalt-mediated...
In sharp contrast with the standard [2 + 2 + 2] cycloaddition reaction of diyne/ene, cobalt-mediated...
In sharp contrast with the standard [2 + 2 + 2] cycloaddition reaction of diyne/ene, cobalt-mediated...
International audienceIn sharp contrast with the standard [2 + 2 + 2] cycloaddition reaction of diyn...
International audienceIn sharp contrast with the standard [2 + 2 + 2] cycloaddition reaction of diyn...
International audienceIn sharp contrast with the standard [2 + 2 + 2] cycloaddition reaction of diyn...
International audienceIn sharp contrast with the standard [2 + 2 + 2] cycloaddition reaction of diyn...
International audienceIn sharp contrast with the standard [2 + 2 + 2] cycloaddition reaction of diyn...
The molecular complexity of recently reported cobalt(III) polycyclic complexes, resulting from an in...
The molecular complexity of recently reported cobalt(III) polycyclic complexes, resulting from an in...
The first transannular [4 + 2] cycloaddition reactions of macrocyclic dicobalt hexacarbonyl–dienyne ...
The first transannular [4 + 2] cycloaddition reactions of macrocyclic dicobalt hexacarbonyl–dienyne ...
The first transannular [4 + 2] cycloaddition reactions of macrocyclic dicobalt hexacarbonyl-dienyne ...
The first transannular [4 + 2] cycloaddition reactions of macrocyclic dicobalt hexacarbonyl-dienyne ...