The copolymers of ethylene and 1-hexene were prepared with half-metallocene titanium complex ([t-BuNSiMe2Flu]TiMe2) and modified methylaluminoxane (MMAO). The initial concentrations of 1-hexene were varied to investigate how the different amounts of comonomer affect on the catalytic activity of copolymerization system and microstructure of the copolymers. It has been found that this catalytic system was not active for hexene polymerization, however, it can be active when ethylene was introduced to perform ethylene-hexene copolymerization. As comonomer, 1-hexene provides positive comonomer effect on the system although very high concentration of 1-hexene was introduced. However, the microstructures of the obtained copolymers, which were exam...
Copolymerization of ethylene with styrene, catalyzed by 1,4-dithiabutanediyl-linked bis(phenolato) t...
Copolymerization of ethylene with styrene, catalyzed by 1,4-dithiabutanediyl-linked bis(phenolato) t...
Copolymerization of ethylene with isoprene (IP) catalyzed by 1,4-dithabutanediyl-linked bis(phenolat...
A new type of post-metallocene polymerization catalyst based on titanium complexes with N,N-dialkylc...
We describe the synthesis of [bis(N-(3-tert-butylsalicylidene)anilinato)] titanium (IV) dichloride (...
New catatytic systems based on N,N-dialkylcarbamato Ti(IV) precursors for copolymerization of ethyle...
New catatytic systems based on N,N-dialkylcarbamato Ti(IV) precursors for copolymerization of ethyle...
New catatytic systems based on N,N-dialkylcarbamato Ti(IV) precursors for copolymerization of ethyle...
New catatytic systems based on N,N-dialkylcarbamato Ti(IV) precursors for copolymerization of ethyle...
New catatytic systems based on N,N-dialkylcarbamato Ti(IV) precursors for copolymerization of ethyle...
Ethylene-propylene copolymerization, using [(Ph)NC(R-2)CHC(R-1)O](2)TiCl2 (R-1 = CF3, Ph, or t-Bu; R...
Copolymerization of ethylene with 1-hexene was carried out using two ansa-fluorenyl titanium derivat...
Copolymerization of ethylene with styrene, catalyzed by 1,4-dithiabutanediyl-linked bis(phenolato) t...
Copolymerization of ethylene with styrene, catalyzed by 1,4-dithiabutanediyl-linked bis(phenolato) t...
Copolymerization of ethylene with styrene, catalyzed by 1,4-dithiabutanediyl-linked bis(phenolato) t...
Copolymerization of ethylene with styrene, catalyzed by 1,4-dithiabutanediyl-linked bis(phenolato) t...
Copolymerization of ethylene with styrene, catalyzed by 1,4-dithiabutanediyl-linked bis(phenolato) t...
Copolymerization of ethylene with isoprene (IP) catalyzed by 1,4-dithabutanediyl-linked bis(phenolat...
A new type of post-metallocene polymerization catalyst based on titanium complexes with N,N-dialkylc...
We describe the synthesis of [bis(N-(3-tert-butylsalicylidene)anilinato)] titanium (IV) dichloride (...
New catatytic systems based on N,N-dialkylcarbamato Ti(IV) precursors for copolymerization of ethyle...
New catatytic systems based on N,N-dialkylcarbamato Ti(IV) precursors for copolymerization of ethyle...
New catatytic systems based on N,N-dialkylcarbamato Ti(IV) precursors for copolymerization of ethyle...
New catatytic systems based on N,N-dialkylcarbamato Ti(IV) precursors for copolymerization of ethyle...
New catatytic systems based on N,N-dialkylcarbamato Ti(IV) precursors for copolymerization of ethyle...
Ethylene-propylene copolymerization, using [(Ph)NC(R-2)CHC(R-1)O](2)TiCl2 (R-1 = CF3, Ph, or t-Bu; R...
Copolymerization of ethylene with 1-hexene was carried out using two ansa-fluorenyl titanium derivat...
Copolymerization of ethylene with styrene, catalyzed by 1,4-dithiabutanediyl-linked bis(phenolato) t...
Copolymerization of ethylene with styrene, catalyzed by 1,4-dithiabutanediyl-linked bis(phenolato) t...
Copolymerization of ethylene with styrene, catalyzed by 1,4-dithiabutanediyl-linked bis(phenolato) t...
Copolymerization of ethylene with styrene, catalyzed by 1,4-dithiabutanediyl-linked bis(phenolato) t...
Copolymerization of ethylene with styrene, catalyzed by 1,4-dithiabutanediyl-linked bis(phenolato) t...
Copolymerization of ethylene with isoprene (IP) catalyzed by 1,4-dithabutanediyl-linked bis(phenolat...