Phosphorus-31 and carbon-13 CPMAS NMR spectra have been obtained for imino(triphenyl)phosphorane and amino(triphenyl)phosphonium bromide. Detailed analysis yields information about the 31P shielding tensor and the 14N quadrupole coupling tensor. The static 31P spectrum of the bromide was also analysed in terms of the relevant tensors. Ab initio calculations at the hf/6-31g* level reproduce the observed data well, except for the isotropic shifts, which require a larger basis set and/or higher level of theory. The orientations of the tensors in the molecular frame are derived for the bromide from the calculations
A series of binary transition metal phosphides (Ni3P, Ni12P5, Ni2P, Ni5P4, NiP, NiP2, FeP, FeP2, FeP...
The complete set of NMR parameters for 17 0 enriched phenylphosphinic acid C6H5HP*O(*OH) is calculat...
1. Direct proof for the phosphorotropic tautomerism, where compounds with a pentacoordinated phospho...
Phosphorus-31 and carbon-13 CPMAS NMR spectra have been obtained for imino(triphenyl)phosphorane and...
Phosphorus-31 and carbon-13 CPMAS NMR spectra have been obtained for imino(triphenyl)phosphorane and...
We report the results of a quantum chemical investigation of the 31P nuclear magnetic resonance (NMR...
Solid-state NMR spectroscopy has been used to obtain information about electronic structure and mole...
Schoeller W. On the structure of the P-iodo-, bromo- and chloro-bis(imino)phosphoranes: A DFT study....
Phosphonium halides are a class of compounds containing a tetrahedral phosphorus cation with a halog...
Gudat D, Hoffbauer W, Rozhenko AB, Schoeller W, Povolotskii MI. NMR spectroscopic and computational ...
A 31P and 13C NMR study of powder and single crystal samples of two phosphoenolpyruvate (PEP) compou...
Rozhenko AB, Povolotskii MI, Schoeller W. Conjugation in phosphabutadienes: Ab initio investigation ...
In this chapter, we attempt to give a systematic analysis of the influence on the 31P chemical shift...
This thesis is concerned with a systematic study of phosphine-containing transition metal complexes ...
An X-ray crystal structure reveals that the attempted deprotonation of cyclopropyl(triphenyl)phospho...
A series of binary transition metal phosphides (Ni3P, Ni12P5, Ni2P, Ni5P4, NiP, NiP2, FeP, FeP2, FeP...
The complete set of NMR parameters for 17 0 enriched phenylphosphinic acid C6H5HP*O(*OH) is calculat...
1. Direct proof for the phosphorotropic tautomerism, where compounds with a pentacoordinated phospho...
Phosphorus-31 and carbon-13 CPMAS NMR spectra have been obtained for imino(triphenyl)phosphorane and...
Phosphorus-31 and carbon-13 CPMAS NMR spectra have been obtained for imino(triphenyl)phosphorane and...
We report the results of a quantum chemical investigation of the 31P nuclear magnetic resonance (NMR...
Solid-state NMR spectroscopy has been used to obtain information about electronic structure and mole...
Schoeller W. On the structure of the P-iodo-, bromo- and chloro-bis(imino)phosphoranes: A DFT study....
Phosphonium halides are a class of compounds containing a tetrahedral phosphorus cation with a halog...
Gudat D, Hoffbauer W, Rozhenko AB, Schoeller W, Povolotskii MI. NMR spectroscopic and computational ...
A 31P and 13C NMR study of powder and single crystal samples of two phosphoenolpyruvate (PEP) compou...
Rozhenko AB, Povolotskii MI, Schoeller W. Conjugation in phosphabutadienes: Ab initio investigation ...
In this chapter, we attempt to give a systematic analysis of the influence on the 31P chemical shift...
This thesis is concerned with a systematic study of phosphine-containing transition metal complexes ...
An X-ray crystal structure reveals that the attempted deprotonation of cyclopropyl(triphenyl)phospho...
A series of binary transition metal phosphides (Ni3P, Ni12P5, Ni2P, Ni5P4, NiP, NiP2, FeP, FeP2, FeP...
The complete set of NMR parameters for 17 0 enriched phenylphosphinic acid C6H5HP*O(*OH) is calculat...
1. Direct proof for the phosphorotropic tautomerism, where compounds with a pentacoordinated phospho...