The method for objective (based on Ritz principle only) and optimal determination of electronic-vibro-rotational (rovibronic) term values from meassured wavenumbers recently proposed in our previous paper is applied for singlet electronic states of $^{11}$BH molecule, namely $X^1\Sigma^+$, $A^1\Pi$, $C'^1\Delta$, $B^1\Sigma^+$, $C^1\Sigma^+$, $D^1\Pi$, $E^1\Sigma^+$, $F^1\Sigma^+$, $G^1\Pi$, $H^1\Delta$, $I^1\Sigma^+$, $J^1\Sigma^+$. All known to authors experimental data on the wavenumbers of rovibronic spectral lines are used. Those are the wavenumber values of 1563 spectral lines of 15 band systems, obtained in 10 different original papers. As a result 529 term values with their standard deviations were derived
Author Institution: Department of Chemistry, Purdue UniversityWe have performed new experiments that...
The paper describes how Born–Oppenheimer breakdown parameters for the rotational constants of diatom...
The vibronic (vibration-electronic) transition probability parameters such as Franck-Condon (FC) fac...
$^{a}$P. Jensen, J. Mol. Spectrosc. 128, 478-501(1988). $^{b}$P. Jensen, M. Brumm, W. P. Kraemer, an...
International audienceIn this paper, we derive the theoretical properties of rovibrational levels be...
Author Institution:Instead of describing molecular spectra in terms of electronic energy plus vibrat...
Author Institution: Department of Chemistry Building 148--72, California Institute of TechnologyThe ...
The purpose of this research project was to investigate the effect of perturbations to two low-lying...
Author Institution: Department of Chemistry, Purdue University, West Lafayette, IN 47907; Department...
H$_2^+$ is the simplest of all molecules and as such an important system for the development of mole...
Author Institution: Department of Chemistry, Dalhousie university; Department of Chemistry, Universi...
$^{1.}$ F.M. Fernandez and J.F. Ogilvie, Phys. Rev. 42 (1990) 4001-4007. $^{2.}$ F.M. Fernandez and ...
Antisymmetrized geminal product wavefunctions with several limited basis sets were calculated for th...
Detailed understanding of the energy-level structure of the quantum states as well as of the rovibro...
The electronic 1\Sigma+ states and potential energy curves have been studied with a view to obtainin...
Author Institution: Department of Chemistry, Purdue UniversityWe have performed new experiments that...
The paper describes how Born–Oppenheimer breakdown parameters for the rotational constants of diatom...
The vibronic (vibration-electronic) transition probability parameters such as Franck-Condon (FC) fac...
$^{a}$P. Jensen, J. Mol. Spectrosc. 128, 478-501(1988). $^{b}$P. Jensen, M. Brumm, W. P. Kraemer, an...
International audienceIn this paper, we derive the theoretical properties of rovibrational levels be...
Author Institution:Instead of describing molecular spectra in terms of electronic energy plus vibrat...
Author Institution: Department of Chemistry Building 148--72, California Institute of TechnologyThe ...
The purpose of this research project was to investigate the effect of perturbations to two low-lying...
Author Institution: Department of Chemistry, Purdue University, West Lafayette, IN 47907; Department...
H$_2^+$ is the simplest of all molecules and as such an important system for the development of mole...
Author Institution: Department of Chemistry, Dalhousie university; Department of Chemistry, Universi...
$^{1.}$ F.M. Fernandez and J.F. Ogilvie, Phys. Rev. 42 (1990) 4001-4007. $^{2.}$ F.M. Fernandez and ...
Antisymmetrized geminal product wavefunctions with several limited basis sets were calculated for th...
Detailed understanding of the energy-level structure of the quantum states as well as of the rovibro...
The electronic 1\Sigma+ states and potential energy curves have been studied with a view to obtainin...
Author Institution: Department of Chemistry, Purdue UniversityWe have performed new experiments that...
The paper describes how Born–Oppenheimer breakdown parameters for the rotational constants of diatom...
The vibronic (vibration-electronic) transition probability parameters such as Franck-Condon (FC) fac...