Long-term evolution and revival structure of Rydberg wave packets

It is known that, after formation, a Rydberg wave packet undergoes a series of collapses and revivals within a time period called the revival time, t_{\rm rev}, at the end of which it is close to its original shape. We study the behavior of Rydberg wave packets on time scales much greater than t_{\rm rev}. We show that after a few revival cycles the wave packet ceases to reform at multiples of the revival time. Instead, a new series of collapses and revivals commences, culminating after a time period t_{\rm sr} \gg t_{\rm rev} with the formation of a wave packet that more closely resembles the initial packet than does the full revival at time t_{\rm rev}. Furthermore, at times that are rational fractions of t_{\rm sr}, the square of the autocorrelation function exhibits large peaks with periodicities that can be expressed as fractions of the revival time t_{\rm rev}. These periodicities indicate a new type of fractional revival occurring for times much greater than t_{\rm rev}. A theoretical explanation of these effects is outlined