\u3cp\u3eIn order to fundamentally understand cobalt catalyst deactivation in Fischer-Tropsch synthesis (FTS) due to parts per million levels of NH\u3csub\u3e3\u3c/sub\u3e in the synthesis gas, the adsorption and decomposition of NH\u3csub\u3e3\u3c/sub\u3e on Co(0001) are investigated experimentally under ultrahigh vacuum (UHV) conditions and theoretically using density functional theory (DFT) calculations. NH\u3csub\u3e3\u3c/sub\u3e desorbs intact from the surface, between 100 and 270 K. In agreement with this, DFT calculations show that the activation barrier for NH\u3csub\u3e3\u3c/sub\u3e decomposition, 105 kJ/mol, is higher than the adsorption energy of NH\u3csub\u3e3\u3c/sub\u3e, 59 kJ/mol. Neither CO\u3csub\u3ead\u3c/sub\u3e nor H\u3c...
\u3cp\u3eOxygenated compounds have previously been detected on spent Co/Al\u3csub\u3e2\u3c/sub\u3eO\...
Fischer-Tropsch synthesis is an attractive process to convert alternative carbon sources, such as bi...
Cobalt catalysts are used on a commercial scale to produce synthetic fuels via the Fischer-Tropsch s...
In order to fundamentally understand cobalt catalyst deactivation in Fischer-Tropsch synthesis (FTS)...
\u3cp\u3eAmmonia adsorption and decomposition on defect-rich hcp-Co(0001) surfaces were investigated...
Ammonia adsorption and decomposition on defect-rich hcp-Co(0001) surfaces were investigated under ul...
\u3cp\u3eMonomeric forms of carbon play a central role in the synthesis of long chain hydrocarbons v...
\u3cp\u3e(Graph Presented) Experiments that provide insight into the elementary reaction steps of C\...
The Fischer-Tropsch (FT) process consists of the reaction of a synthesis gas (syngas) mixture contai...
\u3cp\u3eThe way in which the triple bond in CO dissociates, a key reaction step in the Fischer–Trop...
The Fischer-Tropsch (FT) process consists of the reaction of a synthesis gas (syngas) mixture contai...
\u3cp\u3e Cobalt catalysts are used on a co...
Identification of the structure sensitivity of nitrogen molecule (N-2) activation and ammonia synthe...
\u3cp\u3eOxygenated compounds have previously been detected on spent Co/Al\u3csub\u3e2\u3c/sub\u3eO\...
Fischer-Tropsch synthesis is an attractive process to convert alternative carbon sources, such as bi...
Cobalt catalysts are used on a commercial scale to produce synthetic fuels via the Fischer-Tropsch s...
In order to fundamentally understand cobalt catalyst deactivation in Fischer-Tropsch synthesis (FTS)...
\u3cp\u3eAmmonia adsorption and decomposition on defect-rich hcp-Co(0001) surfaces were investigated...
Ammonia adsorption and decomposition on defect-rich hcp-Co(0001) surfaces were investigated under ul...
\u3cp\u3eMonomeric forms of carbon play a central role in the synthesis of long chain hydrocarbons v...
\u3cp\u3e(Graph Presented) Experiments that provide insight into the elementary reaction steps of C\...
The Fischer-Tropsch (FT) process consists of the reaction of a synthesis gas (syngas) mixture contai...
\u3cp\u3eThe way in which the triple bond in CO dissociates, a key reaction step in the Fischer–Trop...
The Fischer-Tropsch (FT) process consists of the reaction of a synthesis gas (syngas) mixture contai...
\u3cp\u3e Cobalt catalysts are used on a co...
Identification of the structure sensitivity of nitrogen molecule (N-2) activation and ammonia synthe...
\u3cp\u3eOxygenated compounds have previously been detected on spent Co/Al\u3csub\u3e2\u3c/sub\u3eO\...
Fischer-Tropsch synthesis is an attractive process to convert alternative carbon sources, such as bi...
Cobalt catalysts are used on a commercial scale to produce synthetic fuels via the Fischer-Tropsch s...