Restrictions on the Material Coefficients in the Constitutive Theories for Non-Classical Viscous Fluent Continua

This paper considers conservation and balance laws and the constitutive theo-ries for non-classical viscous fluent continua without memory, in which in-ternal rotation rates due to the velocity gradient tensor are incorporated in the thermodynamic framework. The constitutive theories for the deviatoric part of the symmetric Cauchy stress tensor and the Cauchy moment tensor are de-rived based on integrity. The constitutive theories for the Cauchy moment tensor are considered when the balance of moments of moments 1) is not a balance law and 2) is a balance law. The constitutive theory for heat vector based on integrity is also considered. Restrictions on the material coefficients in the constitutive theories for the stress tensor, moment tensor, and heat vector are established using the conditions resulting from the entropy inequa-lity, keeping in mind that the constitutive theories derived here based on inte-grity are in fact nonlinear constitutive theories. It is shown that in the case of the simplest linear constitutive theory for stress tensor used predominantly for compressible viscous fluids, Stokes’ hypothesis or Stokes’ assumption has no thermodynamic basis, hence may be viewed incorrect. Thermodynamically consistent derivations of the restrictions on various material coefficients are presented for non-classical as well as classical theories that are applicable to nonlinear constitutive theories, which are inevitable if the constitutive theo-ries are derived based on integrity