Photochemical reactions of metal carbonyls [M(CO)6 (M=Cr, Mo, W), Re(CO)5Br, Mn(CO)3Cp] with salicylaldehyde ethanesulfonylhydrazone (Hsalesh)

The new complexes, M(CO)5(Hsalesh) (M?=?Cr (1), Mo (2), W (3)), Re(CO)4Br(Hsalesh) (4) and Mn(CO)3(Hsalesh) (5) have been synthesized by the photochemical reaction of metal carbonyls M(CO)6 (M?=?Cr, Mo, W), Re(CO)5Br, and Mn(CO)3Cp with salicylaldehyde ethanesulfonyl hydrazone (Hsalesh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR and 1H NMR spectroscopy. The spectroscopic studies show that Hsalesh behaves as a monodentate ligand coordinating via imine N donor atom in M(CO)5(Hsalesh) (M?=?Cr, Mo, W) and Re(CO)4Br(Hsalesh) and as a tridentate ligand in Mn(CO) 3(salesh).05-98/24This research was supported by Gazi University Research Found under Project No. 05-98/24. We thank BP (Turkey) for the provision of photochemical apparatus and Research Foundation of Ege. We thank TUBITAK_ for allocation of time at the NMR, mass spectra and elemental analyses. -