Development of an Alkaloid-Pyrone Annulation: Synthesis of Pleiomaltinine

Ziegler, Robert E.
Tan, Shin Jowl
Kam, Toh Seok
Porco, John A.

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Publication date

January 2012

DOI

10.1002/anie.201204093

Publisher

Wiley

Abstract

Odd Couple: A method for the synthesis of alkaloid-pyrones using a novel pyrone annulation of β-carbolines and indoles with 3-siloxy-4-pyrones is reported. The approach has enabled synthesis of the unusual alkaloid-pyrone pleiomaltinine from the plant-derived indole-alkaloid pleiocarpamine (see Scheme; TBS= tert-butyldimethylsilyl). © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

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Development of an Alkaloid-Pyrone Annulation: Synthesis of Pleiomaltinine

Abstract

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Development of an Alkaloid-Pyrone Annulation: Synthesis of Pleiomaltinine

Abstract

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