Abstract: The photostimulated reaction of Me3Sn- ion with mono, di and trichloro arenes in liquid ammonia gave very good yields of stannanes by the SRN1 mechanism. These products reacted by a palladium-catalized cross coupling reaction with halobenzenes to give phenylated products also in very goods yields. Similar yields can be obtained in one-pot reactions
1,2-Bis(trimethylstannyl)benzene (1) and 2,2′-bis(trimethylstannyl)-1,1′-binaphthyl (2), useful as i...
The relative reactivities of vinylstannanes 2a,b and 4a,b in a Stille coupling with vinyl bromide we...
Under basic conditions aryl halides can undergo SRN1 reactions, BHAS reactions and benzyne formation...
A series of arylstannanes have been synthesized, through an SRN1 mechanism, in good to excellent yie...
The SRN1 reactions of trimethylstannyl and triphenylstannyl anions, and other tin nucleophiles with ...
Sandmeyer-type stannylation: Stille coupling is one of the most powerful coupling reactions for C?C ...
A review on the reactions of triorganyl stannyl ions with haloarenes is presented. Emphasis on the s...
Solvent-free protocols for palladium-catalyzed stannylation of aryl halides, Stille cross-coupling, ...
The reactions of readily aVailable 1,1-dichlorocyclopropanes, obtained by addition of dichlorocarben...
The palladium-catalyzed cross-coupling reaction of methyl (Z)-2,3-bis(tributylstannyl)butenoate wit...
The palladium-catalyzed cross-coupling reaction of methyl (Z)-2,3-bis(tributylstannyl)butenoate with...
In a search for unambiguous examples of the vinylic S(RN)1 route, vinyl bromides Ph(CH3)C=CHBr (10),...
The direct formation of Sn-C bonds from allylic and propargylic CH-bonds has been demonstrated by em...
A synthetic method based on Sandmeyer-type reactions to access both tin- and boron-substituted arene...
A synthetic method based on Sandmeyer-type reactions to access both tin- and boron-substituted arene...
1,2-Bis(trimethylstannyl)benzene (1) and 2,2′-bis(trimethylstannyl)-1,1′-binaphthyl (2), useful as i...
The relative reactivities of vinylstannanes 2a,b and 4a,b in a Stille coupling with vinyl bromide we...
Under basic conditions aryl halides can undergo SRN1 reactions, BHAS reactions and benzyne formation...
A series of arylstannanes have been synthesized, through an SRN1 mechanism, in good to excellent yie...
The SRN1 reactions of trimethylstannyl and triphenylstannyl anions, and other tin nucleophiles with ...
Sandmeyer-type stannylation: Stille coupling is one of the most powerful coupling reactions for C?C ...
A review on the reactions of triorganyl stannyl ions with haloarenes is presented. Emphasis on the s...
Solvent-free protocols for palladium-catalyzed stannylation of aryl halides, Stille cross-coupling, ...
The reactions of readily aVailable 1,1-dichlorocyclopropanes, obtained by addition of dichlorocarben...
The palladium-catalyzed cross-coupling reaction of methyl (Z)-2,3-bis(tributylstannyl)butenoate wit...
The palladium-catalyzed cross-coupling reaction of methyl (Z)-2,3-bis(tributylstannyl)butenoate with...
In a search for unambiguous examples of the vinylic S(RN)1 route, vinyl bromides Ph(CH3)C=CHBr (10),...
The direct formation of Sn-C bonds from allylic and propargylic CH-bonds has been demonstrated by em...
A synthetic method based on Sandmeyer-type reactions to access both tin- and boron-substituted arene...
A synthetic method based on Sandmeyer-type reactions to access both tin- and boron-substituted arene...
1,2-Bis(trimethylstannyl)benzene (1) and 2,2′-bis(trimethylstannyl)-1,1′-binaphthyl (2), useful as i...
The relative reactivities of vinylstannanes 2a,b and 4a,b in a Stille coupling with vinyl bromide we...
Under basic conditions aryl halides can undergo SRN1 reactions, BHAS reactions and benzyne formation...
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