ii ACKNOWLEDGMENTS First of all, I would like to give my deepest thankful wish to my graduate advisor Dr. Nicholas Materer for his great help and guidance during my graduate school life. I have received a lot of benefit from his teaching and suggestions. His prolific knowledge and experience have greatly expanded my science insight. I would also like to thank Dr. John Gelder for his generous help with my teaching assistant career at OSU. I wish to thank Dr. Allen Apblett, Dr. Jeffery White and Dr. John Mintmire for being my committee members and spending efforts and time on helping me with my dissertation. I want to appreciate Dr. Asfaha Iob for his great support to my teaching assistant career, Dr. Richard Bunce for his thoughtful and inte...