Samples of cis,cis- and trans,trans-1,4-difluorobutadiene-1-d1 and of trans,trans-1,4-difluorobutadiene-1,4-d2 have been synthesized, and high-resolution (⩽0.0018 cm−1) infrared spectra of these substances have been recorded in the gas phase. Analysis of the rotational structure, mostly in C-type bands, has yielded ground state rotational constants. For the two 1-d1 species more than one band has been analyzed. For the 1,4-d2 species only one band was available for analysis. However, good agreement between the experimental centrifugal distortion constants and those predicted with a B3LYP/cc-pVTZ model give strong support to the analysis of the very dense spectrum. The ground state rotational constants are a contribution to finding semiexper...
For comparison to the structure of the cis isomer with its puzzlingly lower energy, the complete str...
Author Institution: Department of Chemistry, Kent State University, Oberlin College, Oberlin, OH 440...
Author Institution: Oberlin College; Department of Chemistry, Oberlin College; Department of Chemist...
Samples of cis,cis- and trans,trans-1,4-difluorobutadiene-1-d1 and of trans,trans-1,4-difluorobutadi...
Pure samples of cis,cis- and trans,trans-1,4-difluorobutadiene-2-d1 have been synthesized, and high-...
Author Institution: Department of Chemistry and Biochemistry, Oberlin College, Oberlin, OH 44074; Pa...
Author Institution: Department of Chemistry and Biochemistry, Oberlin College, Oberlin, OH 44074; En...
Author Institution: Department of Chemistry and Biochemistry, Oberlin College, Oberlin, OH 44074; En...
Author Institution: Department of Chemistry; and Biochemistry, Oberlin College, Oberlin, OH 44074;...
Author Institution: Physikalisch-Chemisches Institut, Oberlin College; Department of Chemistry, Ober...
Author Institution: Department of Chemistry, Oberlin College; Physikalisch-Chemisches-Institut der J...
Author Institution: Department of Chemistry, Oberlin College; Department of Chemistry, EMSL, Pacific...
Author Institution: Department of Chemistry, Oberlin College; Department of Chemistry, University of...
Microwave spectra for seven isotopomers of cis-1,2-difluoroethylene have been reinvestigated and ext...
Infrared and Raman spectra were recorded for the trans,trans (EE), cis,cis (ZZ), and cis,trans (ZE) ...
For comparison to the structure of the cis isomer with its puzzlingly lower energy, the complete str...
Author Institution: Department of Chemistry, Kent State University, Oberlin College, Oberlin, OH 440...
Author Institution: Oberlin College; Department of Chemistry, Oberlin College; Department of Chemist...
Samples of cis,cis- and trans,trans-1,4-difluorobutadiene-1-d1 and of trans,trans-1,4-difluorobutadi...
Pure samples of cis,cis- and trans,trans-1,4-difluorobutadiene-2-d1 have been synthesized, and high-...
Author Institution: Department of Chemistry and Biochemistry, Oberlin College, Oberlin, OH 44074; Pa...
Author Institution: Department of Chemistry and Biochemistry, Oberlin College, Oberlin, OH 44074; En...
Author Institution: Department of Chemistry and Biochemistry, Oberlin College, Oberlin, OH 44074; En...
Author Institution: Department of Chemistry; and Biochemistry, Oberlin College, Oberlin, OH 44074;...
Author Institution: Physikalisch-Chemisches Institut, Oberlin College; Department of Chemistry, Ober...
Author Institution: Department of Chemistry, Oberlin College; Physikalisch-Chemisches-Institut der J...
Author Institution: Department of Chemistry, Oberlin College; Department of Chemistry, EMSL, Pacific...
Author Institution: Department of Chemistry, Oberlin College; Department of Chemistry, University of...
Microwave spectra for seven isotopomers of cis-1,2-difluoroethylene have been reinvestigated and ext...
Infrared and Raman spectra were recorded for the trans,trans (EE), cis,cis (ZZ), and cis,trans (ZE) ...
For comparison to the structure of the cis isomer with its puzzlingly lower energy, the complete str...
Author Institution: Department of Chemistry, Kent State University, Oberlin College, Oberlin, OH 440...
Author Institution: Oberlin College; Department of Chemistry, Oberlin College; Department of Chemist...