The oxidation state switching of cerium in cerium oxide nanoparticles is studied in detail. The influence of synthesis medium, aging time, and local environment on the oxidation state switching, between +3 and +4, is analyzed by tracking the absorption edge using UV-visible spectroscopy. It is observed that by tuning the local environment, the chemistry of the nanoparticles could be altered. These time-dependent, environmentally induced changes likely contribute to inconsistencies in the literature regarding quantum-confinement effects for ceria nanoparticles. The results in this Article indicate that there is a need to carry out comprehensive analysis of nanoparticles while considering the influence of synthesis and processing conditions, ...
Cerium oxide (ceria) nanostructures are important in different applications due to their unique char...
A room temperature, template-free, wet chemical synthesis of ceria nanoparticles and their long term...
Ceria nanoparticles (NPs), due to their widespread applications, have attracted a lot of concern abo...
The oxidation state switching of cerium in cerium oxide nanoparticles is studied in detail. The infl...
Cerium oxide (ceria) nanoparticles are widely studied for their current and potential use in catalyt...
Cerium oxide (ceria)-based materials in the nanoscale regime are of significant fundamental and tech...
Ceria nanoparticles (NPs) rapidly and easily cycle between Ce(III) and Ce(IV) oxidation states, maki...
Ceria nanoparticles (NPs) rapidly and easily cycle between Ce(III) and Ce(IV) oxidation states, maki...
Nanoscale cerium oxide is of increasing interest in catalysis, biomedicine, renewable energy, and ma...
Nanomaterials, with potential application as bio-medicinal agents, exploit the chemical properties o...
Abstract The redox performance of CeO2 − x nanocrystals (nanoceria) is always accompanied by the swi...
Nanomaterials, with potential application as bio-medicinal agents, exploit the chemical properties o...
Ceria nanoparticles (NPs) rapidly and easily cycle between Ce(III) and Ce(IV) oxidation states, ma...
A room temperature, template-free, wet chemical synthesis of ceria nanoparticles and their long term...
An accurate description of the structural and chemical modifications of cerium oxide nanoparticles (...
Cerium oxide (ceria) nanostructures are important in different applications due to their unique char...
A room temperature, template-free, wet chemical synthesis of ceria nanoparticles and their long term...
Ceria nanoparticles (NPs), due to their widespread applications, have attracted a lot of concern abo...
The oxidation state switching of cerium in cerium oxide nanoparticles is studied in detail. The infl...
Cerium oxide (ceria) nanoparticles are widely studied for their current and potential use in catalyt...
Cerium oxide (ceria)-based materials in the nanoscale regime are of significant fundamental and tech...
Ceria nanoparticles (NPs) rapidly and easily cycle between Ce(III) and Ce(IV) oxidation states, maki...
Ceria nanoparticles (NPs) rapidly and easily cycle between Ce(III) and Ce(IV) oxidation states, maki...
Nanoscale cerium oxide is of increasing interest in catalysis, biomedicine, renewable energy, and ma...
Nanomaterials, with potential application as bio-medicinal agents, exploit the chemical properties o...
Abstract The redox performance of CeO2 − x nanocrystals (nanoceria) is always accompanied by the swi...
Nanomaterials, with potential application as bio-medicinal agents, exploit the chemical properties o...
Ceria nanoparticles (NPs) rapidly and easily cycle between Ce(III) and Ce(IV) oxidation states, ma...
A room temperature, template-free, wet chemical synthesis of ceria nanoparticles and their long term...
An accurate description of the structural and chemical modifications of cerium oxide nanoparticles (...
Cerium oxide (ceria) nanostructures are important in different applications due to their unique char...
A room temperature, template-free, wet chemical synthesis of ceria nanoparticles and their long term...
Ceria nanoparticles (NPs), due to their widespread applications, have attracted a lot of concern abo...