The interaction between Fe(II)-Fe(III) in strong acidic solution has been investigated by means of electronic and Raman spectra, magnetic susceptibility measurement and chemical analysis of the solution. It was found that the green intermediate complex having an absorption band at 337 nm was formed on oxidation of Fe(H_2O)^_6 in perchloric acid solution. The Fe(II)/Fe(III) ratio in the green complex was a third. The configuration of the complex consisting of Fe(II)-O-Fe(III) oxo-bridges was suggested
Equilibrium and kinetic studies were performed to investigate the complexation of aqueous high spin ...
Department of Physical Chemistry, Jadavpur University, Calcutta-32 Received 16 December 1970; revis...
Department of Chemistry, Jadavpur University, Calcutta-32 Manuscript received 8 October 1975; accep...
The formation of Fe(II)-Fe(III)-intermediate green complex in aqueous solutions has been investigate...
Hydroxyl complexation in the Fe(III)–Fe(II)–Na(H)CI-H2O system at different ionic strengths of the s...
Department of Physical Chemistry, Jadavpur University, Calcutta-32 Received 16 December 1970; revis...
The complex formation between the Fe3+ ion and 2-hydroxybenzohydroxamic acid (salicylhydroxamic acid...
N-Phenyl salicylhydroxamic acid (RH2) forms coloured complexes with Fe(III). The compositions of the...
On the basis of affinity of Fe(III) ions toward functional groups of 2,6-dihydroxy benzoic acid (2,6...
Iron (lII) forms in the aqueous medium a green complex with 5-chloro 8-hydroxy quinoline 7-sulfonic ...
The formation of an Fe-III-OOH species by reaction of complex 1 ([(MeN3Py)Fe-II(CH3CN)(2)](2+)) with...
The reaction involving 2,6-diformyl-4-methylphenol, 1,3-diaminopropane, iron(II) perchlorate and sod...
The green complex formed by iron (II) with 4-isonitroso-1-phenyl-3-methylpyrazolone-5 in acidic medi...
Fe3+ ion forms a blue, water-soluble complex with 2-hydroxy-3-naphthoie acid with maximum absorbance...
Electron spectroscopy combined with the computer simulation of experimental data is employed to stud...
Equilibrium and kinetic studies were performed to investigate the complexation of aqueous high spin ...
Department of Physical Chemistry, Jadavpur University, Calcutta-32 Received 16 December 1970; revis...
Department of Chemistry, Jadavpur University, Calcutta-32 Manuscript received 8 October 1975; accep...
The formation of Fe(II)-Fe(III)-intermediate green complex in aqueous solutions has been investigate...
Hydroxyl complexation in the Fe(III)–Fe(II)–Na(H)CI-H2O system at different ionic strengths of the s...
Department of Physical Chemistry, Jadavpur University, Calcutta-32 Received 16 December 1970; revis...
The complex formation between the Fe3+ ion and 2-hydroxybenzohydroxamic acid (salicylhydroxamic acid...
N-Phenyl salicylhydroxamic acid (RH2) forms coloured complexes with Fe(III). The compositions of the...
On the basis of affinity of Fe(III) ions toward functional groups of 2,6-dihydroxy benzoic acid (2,6...
Iron (lII) forms in the aqueous medium a green complex with 5-chloro 8-hydroxy quinoline 7-sulfonic ...
The formation of an Fe-III-OOH species by reaction of complex 1 ([(MeN3Py)Fe-II(CH3CN)(2)](2+)) with...
The reaction involving 2,6-diformyl-4-methylphenol, 1,3-diaminopropane, iron(II) perchlorate and sod...
The green complex formed by iron (II) with 4-isonitroso-1-phenyl-3-methylpyrazolone-5 in acidic medi...
Fe3+ ion forms a blue, water-soluble complex with 2-hydroxy-3-naphthoie acid with maximum absorbance...
Electron spectroscopy combined with the computer simulation of experimental data is employed to stud...
Equilibrium and kinetic studies were performed to investigate the complexation of aqueous high spin ...
Department of Physical Chemistry, Jadavpur University, Calcutta-32 Received 16 December 1970; revis...
Department of Chemistry, Jadavpur University, Calcutta-32 Manuscript received 8 October 1975; accep...