Add to ORKGStructural variation of several types of amidine-based catalysts was explored, including variation of steric, electronic and other parameters. Enantioselective Steglich and related rearrangements were explored using HBTM-type catalysts previously developed in our group. Rearrangement of several oxazolyl carbonates revealed that phenoxycarbonyl migrating group is optimal. Rearrangement of benzofuran and oxindole enolcarbonates proceeded, but with only low enantioselectivity
Kinetic resolution of racemic alcohols has been traditionally achieved via enzymatic enantioselectiv...
The oxidative N-acylation reaction of 3,4-dihydropyrimidin-2-(1H)-ones (DHPMs) with enals and N-hete...
This thesis presents the application and development of H-bond donor organocatalysts. Chapter 2 pre...
Structural variation of several types of amidine-based catalysts was explored, including variation o...
A dual-catalysis approach, namely the combination of an achiral nucleophilic catalyst and a chiral a...
The evaluation of a range of enantiomerically pure NHCs, prepared in situ from imidazolinium or tria...
Dietz FR, Gröger H. Novel catalytic synthetic route to protected alpha-methyl threonine and the firs...
Among the fundamental chemical transformations in organic synthesis, rearrangement has been recogniz...
This thesis details the development of enantioselective, isothiourea-catalysed, acyl-transfer metho...
A new chiral 4-(dimethylamino)pyridine (DMAP) analog was developed that used restricted rotation to ...
Acyl-transfer reactions have become commonplace in organic synthesis and organocatalysis of these re...
This thesis describes an extensive investigation of the O- to C-carboxyl transfer of oxazolyl carbon...
The structural motif within a series of tetrahydropyrimidine-based isothioureas necessary for genera...
The catalytic kinetic resolution of cyclic amines with achiral N-heterocyclic carbenes and chiral hy...
A highly enantioselective a-ketol rearrangement has been developed. In the presence of a chiral Cu-b...
Kinetic resolution of racemic alcohols has been traditionally achieved via enzymatic enantioselectiv...
The oxidative N-acylation reaction of 3,4-dihydropyrimidin-2-(1H)-ones (DHPMs) with enals and N-hete...
This thesis presents the application and development of H-bond donor organocatalysts. Chapter 2 pre...
Structural variation of several types of amidine-based catalysts was explored, including variation o...
A dual-catalysis approach, namely the combination of an achiral nucleophilic catalyst and a chiral a...
The evaluation of a range of enantiomerically pure NHCs, prepared in situ from imidazolinium or tria...
Dietz FR, Gröger H. Novel catalytic synthetic route to protected alpha-methyl threonine and the firs...
Among the fundamental chemical transformations in organic synthesis, rearrangement has been recogniz...
This thesis details the development of enantioselective, isothiourea-catalysed, acyl-transfer metho...
A new chiral 4-(dimethylamino)pyridine (DMAP) analog was developed that used restricted rotation to ...
Acyl-transfer reactions have become commonplace in organic synthesis and organocatalysis of these re...
This thesis describes an extensive investigation of the O- to C-carboxyl transfer of oxazolyl carbon...
The structural motif within a series of tetrahydropyrimidine-based isothioureas necessary for genera...
The catalytic kinetic resolution of cyclic amines with achiral N-heterocyclic carbenes and chiral hy...
A highly enantioselective a-ketol rearrangement has been developed. In the presence of a chiral Cu-b...
Kinetic resolution of racemic alcohols has been traditionally achieved via enzymatic enantioselectiv...
The oxidative N-acylation reaction of 3,4-dihydropyrimidin-2-(1H)-ones (DHPMs) with enals and N-hete...
This thesis presents the application and development of H-bond donor organocatalysts. Chapter 2 pre...