A comparative study of the copper metallocenter coordination sphere is carried out for a series of N-substituted β-alaninate ligands in condensed phase. For the elucidation of the effect of regular changes in dentate properties of a ligand on the complex structure, N-(bis(hydroxymethyl)methyl)- β-alanine and its copper(II) complex are specially synthesized and the complex structure is studied by the method of X-ray structural analysis. For determination of structure of the complexes in aqueous solution is applied electron spin resonance spectroscopy. Structural characteristics of β-alaninate and glycinate complexes are compared. The factors promoting formation of polynuclear complexes are considered. © 2009 Pleiades Publishing, Ltd
The work embodied in this thesis was carried out by the author in the Department of Applied Chemistr...
As part of our continuing investigations of the influence of stereochemical demands of ligands on th...
Abstract Binary and ternary complexes of copper(II) with L-glutamic acid (Glu) and diamines 1,3-diam...
The synthesys and crystal structure of three copper complexes with N-tosyl-aminoacids are reported. ...
Ternary complexes of the type [CuL2(mim)2][L =N-acetyl-α-, N-benzoyl-α-, N-acetyl-β-, or N-benzoyl-β...
The article presents an overview of the results achieved during the last several decades on the synt...
The complex formation between copper(II) and a polyampholyte ligand derived from α-alanine and 1,4-b...
[[abstract]]A series of biouclear copper (II) complexes containing a-diimine ligand has been synthes...
Bis(N-acetyl-L-alaninato)copper(II) monohydrate and its adducts with cyclic aliphatic and aromatic ...
Structural features and dynamical behaviour of the copper(ii) bis-complexes with glycine, d-alanine,...
Mixed-ligand complexes of the type CuL2(IM)2 (L= N-protected aminoacidate= benzoylglycinate (hippura...
A blue and a green compound of the type Cu(Ac-beta-ala)2 x2H20 and a green compound of the type [Cu(...
Reaction of amines with the complex [Cu(Bz-AlaO)2]\ub7H2O (Bz-AlaO =N-benzoyl-DL-alaninato) gives ad...
A total of five dinuclear copper complexes were synthesized using 4,6-O-butylidene/ethylidene-N-(alp...
The neutral six-coordinated tetragonal Co(β-ala)2•2H2O complex(β-ala = NH2CH2CH2COO−) was prepared. ...
The work embodied in this thesis was carried out by the author in the Department of Applied Chemistr...
As part of our continuing investigations of the influence of stereochemical demands of ligands on th...
Abstract Binary and ternary complexes of copper(II) with L-glutamic acid (Glu) and diamines 1,3-diam...
The synthesys and crystal structure of three copper complexes with N-tosyl-aminoacids are reported. ...
Ternary complexes of the type [CuL2(mim)2][L =N-acetyl-α-, N-benzoyl-α-, N-acetyl-β-, or N-benzoyl-β...
The article presents an overview of the results achieved during the last several decades on the synt...
The complex formation between copper(II) and a polyampholyte ligand derived from α-alanine and 1,4-b...
[[abstract]]A series of biouclear copper (II) complexes containing a-diimine ligand has been synthes...
Bis(N-acetyl-L-alaninato)copper(II) monohydrate and its adducts with cyclic aliphatic and aromatic ...
Structural features and dynamical behaviour of the copper(ii) bis-complexes with glycine, d-alanine,...
Mixed-ligand complexes of the type CuL2(IM)2 (L= N-protected aminoacidate= benzoylglycinate (hippura...
A blue and a green compound of the type Cu(Ac-beta-ala)2 x2H20 and a green compound of the type [Cu(...
Reaction of amines with the complex [Cu(Bz-AlaO)2]\ub7H2O (Bz-AlaO =N-benzoyl-DL-alaninato) gives ad...
A total of five dinuclear copper complexes were synthesized using 4,6-O-butylidene/ethylidene-N-(alp...
The neutral six-coordinated tetragonal Co(β-ala)2•2H2O complex(β-ala = NH2CH2CH2COO−) was prepared. ...
The work embodied in this thesis was carried out by the author in the Department of Applied Chemistr...
As part of our continuing investigations of the influence of stereochemical demands of ligands on th...
Abstract Binary and ternary complexes of copper(II) with L-glutamic acid (Glu) and diamines 1,3-diam...