‘The puzzle of rare earth spectra in solids’, a term first coined by van Vleck, was solved 30 years ago by Judd and Ofelt. The rich variety of sharp optical absorption and emission lines characteristic of 4f N →4f N lanthanide transitions are parity forbidden in the free ions. However, in the quantitative Judd-Ofelt theory, observation of these transitions is explained through simple configuration mixing caused by a noncentrosymmetric crystal field, allowing opposite-parity excited configurations to become slightly mixed into 4f N
International audienceWe present a modified version of the Judd-Ofelt theory, which describes the in...
For most symmetries the standard parametrization of one-photon electric-dipole transitions between c...
For most symmetries the standard parametrization of one-photon electric-dipole transitions between c...
‘The puzzle of rare earth spectra in solids’, a term first coined by van Vleck, was solved 30 years ...
‘The puzzle of rare earth spectra in solids’, a term first coined by van Vleck, was solved 30 years ...
‘The puzzle of rare earth spectra in solids’, a term first coined by van Vleck, was solved 30 years ...
The theory on the intensities of 4f-4f transitions introduced by B.R. Judd and G.S. Ofelt in 1962 ha...
Broad peaks observed in the photoabsorption spectra of rare earths ∼10-20 eV above the 4d edge are a...
We expand upon recent quantitative calculations which show that numerous parity‐ and spin‐forbidden ...
We expand upon recent quantitative calculations which show that numerous parity‐ and spin‐forbidden ...
The origin of the spectra of rare earth ions arising from f → f and f → d transitions is discussed. ...
We expand upon recent quantitative calculations which show that numerous parity‐ and spin‐forbidden ...
We expand upon recent quantitative calculations which show that numerous parity‐ and spin‐forbidden ...
Broad peaks observed in the photoabsorption spectra of rare earths ∼10-20 eV above the 4d edge are a...
International audienceWe present a modified version of the Judd-Ofelt theory, which describes the in...
International audienceWe present a modified version of the Judd-Ofelt theory, which describes the in...
For most symmetries the standard parametrization of one-photon electric-dipole transitions between c...
For most symmetries the standard parametrization of one-photon electric-dipole transitions between c...
‘The puzzle of rare earth spectra in solids’, a term first coined by van Vleck, was solved 30 years ...
‘The puzzle of rare earth spectra in solids’, a term first coined by van Vleck, was solved 30 years ...
‘The puzzle of rare earth spectra in solids’, a term first coined by van Vleck, was solved 30 years ...
The theory on the intensities of 4f-4f transitions introduced by B.R. Judd and G.S. Ofelt in 1962 ha...
Broad peaks observed in the photoabsorption spectra of rare earths ∼10-20 eV above the 4d edge are a...
We expand upon recent quantitative calculations which show that numerous parity‐ and spin‐forbidden ...
We expand upon recent quantitative calculations which show that numerous parity‐ and spin‐forbidden ...
The origin of the spectra of rare earth ions arising from f → f and f → d transitions is discussed. ...
We expand upon recent quantitative calculations which show that numerous parity‐ and spin‐forbidden ...
We expand upon recent quantitative calculations which show that numerous parity‐ and spin‐forbidden ...
Broad peaks observed in the photoabsorption spectra of rare earths ∼10-20 eV above the 4d edge are a...
International audienceWe present a modified version of the Judd-Ofelt theory, which describes the in...
International audienceWe present a modified version of the Judd-Ofelt theory, which describes the in...
For most symmetries the standard parametrization of one-photon electric-dipole transitions between c...
For most symmetries the standard parametrization of one-photon electric-dipole transitions between c...