Add to ORKGTwo routes with distinct intermediates were chosen in the ongoing research to synthesize a mixed phosphine complex with the formula cis-Re2(O2R)2Cl2(dppm)/(dppmCN). Of these two routes, route 1 resulted in the successful synthesize of the compound Re2(O2CCH3)Cl4(dppmCN)2; this compound is notable as it is a new compound in this field of chemistry and the structure has been verified by x-ray crystallography through VT labs. This presentation will focus on the background work leading up to the synthesize of Re2(O2CCH3)Cl4(dppmCN)2 and its role in current research
Reaction of the potentially tetradentate ligand N,N'-bis[2-(diphenylphosphino)phenyl]propane-1,3-dia...
Reaction of [Re2(CO)9(MeCN)] with cis-1,2-bis(diphenylphosphino)ethylene (cis-Ph2PCH=CHPPh2) in boil...
The intermediacy of Re$\sb2$(O$\sb2$CCH$\sb3)\sb2$Cl$\sb4$ in the conversion of Re$\sb2$(O$\sb2$CCH$...
Oxidative decarbonylation of Re2(CO)10 by Me3NO in a mixture of THF and MeOH followed by addition of...
The main goal of this research was to assign chemical shift values to the methylene hydrogens of dpp...
Dirhenium(II) complexes that contain two bridging Ph2PCH2PPh2 (dppm) ligands are known to adopt one ...
The bis(phosphine), Ph2PN(CH3)CH2CH2N(CH3)PPh2 reacts with Group 6 metal carbonyl derivatives, [ReBr...
The complexes (n-Bu4N)2Re 2Cl8 and cis-Re2(O2CCH 3)2Cl4L2 (L = H2O or py) react with dcpm (dcpm = Cy...
Oxidation of [Re(CO)5]- by a molar equivalent of PPh2Cl at ca. -70°C yielded three dinuclear complex...
Part I describes the synthesis of the fac-cis and mer-trans isomers of ReOCl3(PEt3) 2 in high yield ...
The synthesis and characterization of a new series of neutral, six-coordinated compounds [ReIIIX3(PN...
3-Cyanopropyl(diphenyl)phosphine was synthesized from chloro(diphenyl)phosphine and 4-chlorobutyroni...
When M2L10 complexes containing two rhenium(III) atoms in a quadruple bond react with an excess of a...
The PN2S chelate N-[N-(3-diphenylphosphinopropionyl)glycyl]-S-tritylcysteine methyl ester [PN2S(Trt)...
Reaction of the potentially tetradentate ligand N,N'-bis[2-(diphenylphosphino)phenyl]propane-1,3-dia...
Reaction of the potentially tetradentate ligand N,N'-bis[2-(diphenylphosphino)phenyl]propane-1,3-dia...
Reaction of [Re2(CO)9(MeCN)] with cis-1,2-bis(diphenylphosphino)ethylene (cis-Ph2PCH=CHPPh2) in boil...
The intermediacy of Re$\sb2$(O$\sb2$CCH$\sb3)\sb2$Cl$\sb4$ in the conversion of Re$\sb2$(O$\sb2$CCH$...
Oxidative decarbonylation of Re2(CO)10 by Me3NO in a mixture of THF and MeOH followed by addition of...
The main goal of this research was to assign chemical shift values to the methylene hydrogens of dpp...
Dirhenium(II) complexes that contain two bridging Ph2PCH2PPh2 (dppm) ligands are known to adopt one ...
The bis(phosphine), Ph2PN(CH3)CH2CH2N(CH3)PPh2 reacts with Group 6 metal carbonyl derivatives, [ReBr...
The complexes (n-Bu4N)2Re 2Cl8 and cis-Re2(O2CCH 3)2Cl4L2 (L = H2O or py) react with dcpm (dcpm = Cy...
Oxidation of [Re(CO)5]- by a molar equivalent of PPh2Cl at ca. -70°C yielded three dinuclear complex...
Part I describes the synthesis of the fac-cis and mer-trans isomers of ReOCl3(PEt3) 2 in high yield ...
The synthesis and characterization of a new series of neutral, six-coordinated compounds [ReIIIX3(PN...
3-Cyanopropyl(diphenyl)phosphine was synthesized from chloro(diphenyl)phosphine and 4-chlorobutyroni...
When M2L10 complexes containing two rhenium(III) atoms in a quadruple bond react with an excess of a...
The PN2S chelate N-[N-(3-diphenylphosphinopropionyl)glycyl]-S-tritylcysteine methyl ester [PN2S(Trt)...
Reaction of the potentially tetradentate ligand N,N'-bis[2-(diphenylphosphino)phenyl]propane-1,3-dia...
Reaction of the potentially tetradentate ligand N,N'-bis[2-(diphenylphosphino)phenyl]propane-1,3-dia...
Reaction of [Re2(CO)9(MeCN)] with cis-1,2-bis(diphenylphosphino)ethylene (cis-Ph2PCH=CHPPh2) in boil...
The intermediacy of Re$\sb2$(O$\sb2$CCH$\sb3)\sb2$Cl$\sb4$ in the conversion of Re$\sb2$(O$\sb2$CCH$...