Glyphosate dynamics in a soil under conventional and no-till systems during a soybean growing season

Glyphosate (GLY) is a non-selective herbicide, heavily used world-wide in agriculture, especially under no-tillage (NT) management. The objectives of this work were i - to determine the temporal and vertical variation of GLY and its main metabolite (AMPA) levels during the soybean cycle in a soil under NT and conventional tillage (CT); ii - to determine the relationship of GLY and AMPA levels variation with different soil properties; and iii - to compare initial and final GLY and AMPA levels in the soil during a crop cycle to infer possible accumulation. GLY and AMPA contents were determined in the A horizon (0–40 cm) of a loam soil from Argentinian Pampas Region, in different dates during soybean crop cycle. Soil physical and chemical properties were also determined. GLY and AMPA were detected in all sampling dates in both treatments (GLY and AMPA contents in the soil ranged between 5.7 and 98.5 μg·kg−1; and 6.6 and 1686.0 μg·kg−1, respectively). GLY was strongly retained in the top soil in most of the sampling dates for both treatments (>80% of total GLY was found in the topsoil - 20 cm). CT treatment showed higher GLY temporal variation, favored by higher values of saturated hydraulic conductivity (K0), total macroporosity (θma) and effective macroporosity (εma), especially when strong precipitation occurred near the application. GLY vertical transport under NT seemed to be limited by low values of K0, θma, and εma. The temporal variation of GLY vertical transport was explained by the temporal variation of the studied soil physical and hydraulic properties. Total extracted GLY accumulated, with an increment between the last and the first sampling date of 54% and 82% during the crop cycle for NT and CT, respectively.Fil: Soracco, Carlos Germán. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales; ArgentinaFil: Villarreal, Rafael. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales; ArgentinaFil: Lozano, Luis Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales; ArgentinaFil: Vittori, Santiago. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Centro de Investigaciones del Medio Ambiente; ArgentinaFil: Melani, Esteban Miguel. Instituto Nacional de Tecnología Agropecuaria; ArgentinaFil: Marino, Damian Jose Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Centro de Investigaciones del Medio Ambiente; Argentin