We combined Raman and infrared vibrational spectroscopies with complementary lattice dynamics calculations and magnetization measurements to reveal the dynamic aspects of charge-lattice-spin coupling in Co[N(CN)(2)](2). Our work uncovers electron-phonon coupling as a magnetic field-driven avoided crossing of the low-lying Co2+ electronic excitation with two ligand phonons and a magnetoelastic effect that signals a flexible local CoN6 environment. Their simultaneous presence indicates the ease with which energy is transferred over multiple length and time scales in this system
The interplay between charge, structure, and magnetism gives rise to rich phase diagrams in complex ...
The authors show that, similarly to electrons, in the presence of spin-orbit coupling, phonons can i...
Single-molecule magnets (SMMs) are of intense interest due to their potential use as molecular data ...
We combined Raman and infrared vibrational spectroscopies with complementary lattice dynamics calcul...
Many of the most attractive properties of multifunctional materials can be traced to the competition...
A combination of inelastic neutron scattering (INS), far-IR magneto-spectroscopy (FIRMS), and Raman ...
A combination of inelastic neutron scattering (INS), far-IR magneto-spectroscopy (FIRMS), and Raman ...
In order to explore the consequences of spin-orbit coupling on spin-phonon interactions in a set of ...
Magnetic interactions in hybrid materials are poorly understood compared to those in purely inorgani...
Large separation of magnetic levels and slow relaxation in metal complexes are desirable properties ...
Spin–phonon coupling plays an important role in single-molecule magnets and molecular qubits. Howeve...
Spin–phonon coupling plays an important role in single-molecule magnets and molecular qubits. Howeve...
We report the discovery of a magnetic quantum critical transition in Mn[N(CN)(2)](2) that drives the...
Molecule-based materials offer unique opportunities to explore the interplay between charge, spin, a...
Realization of the full technological potential of molecular magnets requires a fundamental understa...
The interplay between charge, structure, and magnetism gives rise to rich phase diagrams in complex ...
The authors show that, similarly to electrons, in the presence of spin-orbit coupling, phonons can i...
Single-molecule magnets (SMMs) are of intense interest due to their potential use as molecular data ...
We combined Raman and infrared vibrational spectroscopies with complementary lattice dynamics calcul...
Many of the most attractive properties of multifunctional materials can be traced to the competition...
A combination of inelastic neutron scattering (INS), far-IR magneto-spectroscopy (FIRMS), and Raman ...
A combination of inelastic neutron scattering (INS), far-IR magneto-spectroscopy (FIRMS), and Raman ...
In order to explore the consequences of spin-orbit coupling on spin-phonon interactions in a set of ...
Magnetic interactions in hybrid materials are poorly understood compared to those in purely inorgani...
Large separation of magnetic levels and slow relaxation in metal complexes are desirable properties ...
Spin–phonon coupling plays an important role in single-molecule magnets and molecular qubits. Howeve...
Spin–phonon coupling plays an important role in single-molecule magnets and molecular qubits. Howeve...
We report the discovery of a magnetic quantum critical transition in Mn[N(CN)(2)](2) that drives the...
Molecule-based materials offer unique opportunities to explore the interplay between charge, spin, a...
Realization of the full technological potential of molecular magnets requires a fundamental understa...
The interplay between charge, structure, and magnetism gives rise to rich phase diagrams in complex ...
The authors show that, similarly to electrons, in the presence of spin-orbit coupling, phonons can i...
Single-molecule magnets (SMMs) are of intense interest due to their potential use as molecular data ...
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