The reactions of the complexes CpCo(CO)L (Cp = cyclopentadienyl, L = CO, PPh3) with ClCH2CN have been investigated. Chloroacetonitrile reacts with CpCo(CO)PPh3 to give the cationic complex [CpCo(CH2CN)(CNCH2Cl)PPh3]+, which has been isolated and characterized. Compounds of the type [CpCo(CH2CN)(bipy)]+ BPh4− and CpCo(CH2CN)PPh3CN have been obtained by substitution reactions
The reactions of [Co(η-C5H5)(PMe3)3][PF6]2 with the nucleophiles Y− = CN−, N3−, MeO−, H−, NO2− have ...
[Co(R-η-C3H4)(η-C5H5)I] is a good precursor for the preparation of some new cationic complexes as th...
The treatment of Br2Co(dotnH) with the C6F5MgBr Grignard reagent leads to the isolation of (C6F5)BrC...
The reactions of the complexes CpCo(CO)L (Cp = cyclopentadienyl, L = CO, PPh3) with ClCH2CN have bee...
The treatment of the aquocation [Co(η3-2-MeC3H4)(η5-C5H5)(H2O]+ with neutral and anionic ligands giv...
M. Sc.This study comprises the preparation and characterisation of new cyclopentadienylmolybdenum ca...
Passage of CO through solutions of complexes (C6F5)2CoL2 gives carbonyl derivatives (C6F5)2CoL2(CO) ...
Cobalt(I) carbonyl complexes of formula [Co(CO)n(P)5−n]ClO4 (n = 1, 2, 3; P = secondary or tertiary ...
Dichloromethyl complexes of the type [Co-(CHCl2)(CNR)nP5-n](PF6)2 [n = 2, 3; R = 4-CH3C6H4, 4-CH3OC6...
The reactions of [Co(η-C5H5)(PMe3)3][PF6]2 with the nucleophiles Y− = CN−, N3−, MeO−, H−, NO2− have ...
[Co(R-η-C3H4)(η-C5H5)I] is a good precursor for the preparation of some new cationic complexes as th...
The treatment of Br2Co(dotnH) with the C6F5MgBr Grignard reagent leads to the isolation of (C6F5)BrC...
The reactions of the complexes CpCo(CO)L (Cp = cyclopentadienyl, L = CO, PPh3) with ClCH2CN have bee...
The treatment of the aquocation [Co(η3-2-MeC3H4)(η5-C5H5)(H2O]+ with neutral and anionic ligands giv...
M. Sc.This study comprises the preparation and characterisation of new cyclopentadienylmolybdenum ca...
Passage of CO through solutions of complexes (C6F5)2CoL2 gives carbonyl derivatives (C6F5)2CoL2(CO) ...
Cobalt(I) carbonyl complexes of formula [Co(CO)n(P)5−n]ClO4 (n = 1, 2, 3; P = secondary or tertiary ...
Dichloromethyl complexes of the type [Co-(CHCl2)(CNR)nP5-n](PF6)2 [n = 2, 3; R = 4-CH3C6H4, 4-CH3OC6...
The reactions of [Co(η-C5H5)(PMe3)3][PF6]2 with the nucleophiles Y− = CN−, N3−, MeO−, H−, NO2− have ...
[Co(R-η-C3H4)(η-C5H5)I] is a good precursor for the preparation of some new cationic complexes as th...
The treatment of Br2Co(dotnH) with the C6F5MgBr Grignard reagent leads to the isolation of (C6F5)BrC...
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