In recent decades, the demand for flax and hemp fibers and annually renewable and biodegradable sources of raw materials is increasing rapidly due to newapplications of innovative materials.Cellulose is most valuable component of bast fibres with a wide application range. Relative content of crystalline cellulose influences mechanical properties offibres. Content and structural composition of lignin determines how severe technologies could be applied to separate crystalline cellulose from matrix.The paper examines the flax and hemp fiber structure and chemical composition of the total comparative analysis, as well as determined and comparedcrystalline and amorphous cellulose composition of several Latvian and grown in Poland fiber flax and ...