Add to ORKGThe photochemistry of trifluoronitrosomethane in an inert gas matrix was investigated using infrared spectroscopy. Fourier Transform IR spectra of CF3NO in argon, krypton, nitrogen, and oxygen at temperatures ranging from 12 to 36 K and high vacuum conditions, on the order of IO-6 torr, were taken. The system was exposed to laser irradiation (He/Ne and diode) and UV photolysis over various time and temperature increments. Analysis of the spectra indicate the formation of a trans-diazoxy photodimer, (CF3NO)2. This structure differs from one characterized by Mason, and is supported by work done by Glaser et al., and Shurvell
Author Institution: Laser Chemistry Institute, Fudan UniversityMatrix isolation combined with Fourie...
Author Institution: University College London, 20 Gordon Street, London, WCIH OAJ, U. K.The formatio...
The IR spectra of S-ethyl fluorothioformate, FC(O)SCH<sub>2</sub>CH<sub>3</sub>, were recorded in ...
$^{a}$ J. Mason, J. Chem. Soc. 1963, 4531.Author Institution: Titleist Foot Joy World Wide; Departme...
$^{1}$ J. Mason, J Chem. Soc 1963, 4531.Author Institution: Department of Chemistry, University of S...
Trifluoromethyl compounds are thought to play a role in the depletion of ozone in the atmosphere. Th...
$^1$ J. Mason, J. Chem. Soc. 1963, 4531.Author Institution: University of Scranton, Scranton, PA 185...
The vapor of acetyl isocyanide, CH3C(O)NCS, and trifluoroacetyl isocyanide, CF3C(O)NCS, were isolate...
Trifluoronitrosomethane (CF3NO) was trapped in rare gas matrixes and irradiated at 633 and 670 nm. T...
The reaction of the CF3 radical with NO2 has been investigated by using time-resolved FTIR emission ...
Author Institution: Sun Chemical Corporation; Department of Chemistry, University of ScrantonSubmono...
Author Institution: Sun Chemical Corporation; Department of Chemistry, University of ScrantonSubmono...
The present study is a contribution to the synthesis and extensive characterization of fundamental C...
The IR spectra of S-ethyl fluorothioformate, FC(O)SCH2CH3, were recorded in the vapor phase and comp...
The research herein investigates two primary methods to synthesize trifluoronitromethane, CF₃NO₂. Th...
Author Institution: Laser Chemistry Institute, Fudan UniversityMatrix isolation combined with Fourie...
Author Institution: University College London, 20 Gordon Street, London, WCIH OAJ, U. K.The formatio...
The IR spectra of S-ethyl fluorothioformate, FC(O)SCH<sub>2</sub>CH<sub>3</sub>, were recorded in ...
$^{a}$ J. Mason, J. Chem. Soc. 1963, 4531.Author Institution: Titleist Foot Joy World Wide; Departme...
$^{1}$ J. Mason, J Chem. Soc 1963, 4531.Author Institution: Department of Chemistry, University of S...
Trifluoromethyl compounds are thought to play a role in the depletion of ozone in the atmosphere. Th...
$^1$ J. Mason, J. Chem. Soc. 1963, 4531.Author Institution: University of Scranton, Scranton, PA 185...
The vapor of acetyl isocyanide, CH3C(O)NCS, and trifluoroacetyl isocyanide, CF3C(O)NCS, were isolate...
Trifluoronitrosomethane (CF3NO) was trapped in rare gas matrixes and irradiated at 633 and 670 nm. T...
The reaction of the CF3 radical with NO2 has been investigated by using time-resolved FTIR emission ...
Author Institution: Sun Chemical Corporation; Department of Chemistry, University of ScrantonSubmono...
Author Institution: Sun Chemical Corporation; Department of Chemistry, University of ScrantonSubmono...
The present study is a contribution to the synthesis and extensive characterization of fundamental C...
The IR spectra of S-ethyl fluorothioformate, FC(O)SCH2CH3, were recorded in the vapor phase and comp...
The research herein investigates two primary methods to synthesize trifluoronitromethane, CF₃NO₂. Th...
Author Institution: Laser Chemistry Institute, Fudan UniversityMatrix isolation combined with Fourie...
Author Institution: University College London, 20 Gordon Street, London, WCIH OAJ, U. K.The formatio...
The IR spectra of S-ethyl fluorothioformate, FC(O)SCH<sub>2</sub>CH<sub>3</sub>, were recorded in ...