Unusual Magnetic Properties of a Two-coordinate Heteroleptic Linear Cobalt(II) Complex
- Ni, Chengbao
- Stich, Troy A.
- Long, Gary J.
- Power, Philip P.
Publication date
January 2010
DOI Publisher
Royal Society of Chemistry (RSC) ISSN
1359-7345 Citation count (estimate)
28Abstract
The synthesis and characterization of two-coordinate cobalt(ii) complexes CoAr′2 (1) and Ar′CoN(SiMe3)2 (2) (Ar′ = C6H3-2,6-(C6H3-2,6- iPr2)2) are reported. The magnetic data for 2 show that it has an unexpectedly high μeff of 5.65 μB whereas the bent complex 1 has a significantly lower moment. © 2010 The Royal Society of Chemistry
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