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Synthesis and Characterization of the Metal(I) Dimers [Ar\u27MMAr\u27]: Comparisons with Quintuple-Bonded [Ar\u27CrCrAr\u27]

  • Nguyen, Tailuan
  • Merrill, W. Alexander
  • Ni, Chengbao
  • Lei, Hao
  • Long, Gary J.
  • Power, Philip P.
  • Fettinger, James C.
  • Ellis, Bobby D.
  • Brynda, Marcin
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Publication date
November 2008
Icon DOI
10.1002/anie.200802657
Publisher
Wiley
ISSN
1433-7851
Citation count (estimate)
41

Abstract

Cobalt together: The iron and cobalt analogues of the quintuple-bonded chromium species [Ar\u27CrCrAr\u27] (Ar\u27 = C6H3-2,6-(2,6-iPr2C6H3)2) are described and their structures investigated by crystallography, magnetic studies, and density functional calculations. Metal-η6-aryl interactions in [Ar\u27FeFeAr\u27] and [Ar\u27CoCoAr\u27] are stronger than those detected in [Ar\u27CrCrAr\u27], whereas metal-metal bonding is much weaker

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