An Insight into Ion-transport by Calixarenes; the Structure of the Dipotassium Complex of P-tert-butylcalix[8]arene Crystallised from a Protogenic, Coordinating Solvent [ethanol/diethylcarbonate (10:1)]
- Clague, Nicholas P.
- Clegg, William
- Coles, Simon J.
- Crane, Jonathan D.
- Moreton, David J.
- Sinn, Ekkehard
- Teat, Simon J.
- Young, Nigel A.
DOIAbstract
The structure of the dipotassium complex of the dianion of p-tert-butylcalix[8]arene crystallised from a protogenic, coordinating solvent (ethanol-diethylcarbonate, 10:1) shows that the metal ions are bound above and below the cavity of the calix[8]arene, which adopts a “pinched” conformation
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