This work consists of two topics. The first part deals with deuterium nuclear magnetic resonance (²H NMR) study of bulk and adsorbed polymers. Segmental dynamics of poly(methyl acrylate) is examined in bulk and when adsorbed to anopore, alumina and silica as a function of temperature. The second part investigates diffusion of small molecules in polymer solutions by pulsed field-gradient proton nuclear magnetic resonance (PGSE ¹H NMR). The diffusion of solvents in polymer solutions is investigated. The diffusion of N-N, dimethylformamide in polystyrene is studied as a function of concentration and temperature. The diffusion coefficients of solvents in binary solvent mixtures of methylene chloride/toluene and chloroform/acetonitrile in poly(m...
1H NMR microscopy has become established as an essential tool for the study of the diffusion of smal...
Deuterium solid-state quadrupole-echo NMR was used to study the effect of molecular weight on the se...
Deuterium solid-state quadrupole-echo NMR techniques were used to probe the dynamics of bulk and sil...
The chain dynamics of polymer molecules in solution has been the subject of much scientific study. P...
In this paper the authors review some of the work which has been done in their laboratory on the dif...
Theoretical treatments of static and dynamic properties of polymer solutions are reviewed. Particula...
NMR diffusion measurements (or dNMR) provide a powerful tool for analysis of solution organization a...
The aim of this study has been to investigate the self-diffusion behaviour in polymer solutions and ...
In this paper the authors describe how Pulsed-Field Gradient, Spin-Echo Nuclear Magnetic Resonance (...
Solvent ingress into polymeric materials is of widespread industrial importance in the context of po...
The self-diffusion coefficient of chloroform in poly(isopropyl acrylate-chloroform solutions has bee...
The interior surface of well-defined porous alumina membranes (Anopore) of 20nm and 200nm pore diame...
With the discovery of NMR in 1940 by F. Block and E. Purcell, disciplines such as chemistry, medicin...
Pulse NMR has been used to study the self-diffusion of the macromolecules of fractionated PS in solu...
Pulsed gradient NMR techniques have been used to study self-diffusion in polymer solutions. The syst...
1H NMR microscopy has become established as an essential tool for the study of the diffusion of smal...
Deuterium solid-state quadrupole-echo NMR was used to study the effect of molecular weight on the se...
Deuterium solid-state quadrupole-echo NMR techniques were used to probe the dynamics of bulk and sil...
The chain dynamics of polymer molecules in solution has been the subject of much scientific study. P...
In this paper the authors review some of the work which has been done in their laboratory on the dif...
Theoretical treatments of static and dynamic properties of polymer solutions are reviewed. Particula...
NMR diffusion measurements (or dNMR) provide a powerful tool for analysis of solution organization a...
The aim of this study has been to investigate the self-diffusion behaviour in polymer solutions and ...
In this paper the authors describe how Pulsed-Field Gradient, Spin-Echo Nuclear Magnetic Resonance (...
Solvent ingress into polymeric materials is of widespread industrial importance in the context of po...
The self-diffusion coefficient of chloroform in poly(isopropyl acrylate-chloroform solutions has bee...
The interior surface of well-defined porous alumina membranes (Anopore) of 20nm and 200nm pore diame...
With the discovery of NMR in 1940 by F. Block and E. Purcell, disciplines such as chemistry, medicin...
Pulse NMR has been used to study the self-diffusion of the macromolecules of fractionated PS in solu...
Pulsed gradient NMR techniques have been used to study self-diffusion in polymer solutions. The syst...
1H NMR microscopy has become established as an essential tool for the study of the diffusion of smal...
Deuterium solid-state quadrupole-echo NMR was used to study the effect of molecular weight on the se...
Deuterium solid-state quadrupole-echo NMR techniques were used to probe the dynamics of bulk and sil...