We describe the historical evolution of the conceptualization, formulation, quantification, application and utilization of “radiative forcing (RF, see e.g., IPCC, 1990)” of Earth’s climate. Basic theories of shortwave and long wave radiation were developed through the 19th and 20th centuries, and established the analytical framework for defining and quantifying the perturbations to the Earth’s radiative energy balance by natural and anthropogenic influences. The insight that the Earth’s climate could be radiatively forced by changes in carbon dioxide, first introduced in the 19th century, gained empirical support with sustained observations of the atmospheric concentrations of the gas beginning in 1957. Advances in laboratory and field m...