Bonding in Uranium(V) Hexafluoride Based on the Experimental Electron Density Distribution Measured at 20 K

International audienceThe electron density distribution of [PPh4][UF6] was obtained from high-resolution X-ray diffrac-tion data measured at 20 K. The electron density was mod-eled with an augmented Hansen-Coppens multipolar formalism. Topological analysis reveals that the U-F bond is of incipient covalent nature. Theoretical calculations add further support to the bonding description gleaned from the experimental model. The impact of the uranium anomalous dispersion terms on the refinement is also discussed