Rhodium(II)-Alkynyl Carbenoids Insertion into Si–H bonds: An Entry to Propargylic Geminal Bis(silanes)

Courant, Thibaut
Kumar, Rahul
Turcaud, Serge
Micouin, Laurent

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Publication date

January 2016

DOI

10.1021/acs.orglett.6b02264

Publisher

American Chemical Society (ACS)

Abstract

International audienceα-Alkynyl-α′-trimethylsilylhydrazones are used as novel Rh(II)-carbenoids precursors. These new carbenoids have shown very good reactivity in Si−H insertion reactions, leading to original propargylic geminal-bis(silanes) in a two-step sequential process

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Rhodium(II)-Alkynyl Carbenoids Insertion into Si–H bonds: An Entry to Propargylic Geminal Bis(silanes)

Abstract

Extracted data

Rhodium(II)-Alkynyl Carbenoids Insertion into Si–H bonds: An Entry to Propargylic Geminal Bis(silanes)

Abstract

Extracted data

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