Transition metal complexes with pyrazole-derived ligands. XI. [Zn(mu-L)(HL)(OAc)](2) (HL is 4-acetyl-3-amino-5-methylpyrazole)

Tomić, Zoran D.
Jacimovic, ZK
Leovac, Vukadin M.
Češljević, Valerija I.

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Publication date

January 2000

DOI

10.1107/S0108270100004881

Publisher

International Union of Crystallography (IUCr)

Journal

Acta Crystallographica Section C Crystal Structure Communications

Abstract

The title compound, bis(mu-4-acetyl-3-amino-5-methylpyrazolato-N-1 :N-2)bis[(acetato-O)(4-acetyl-3-amino-5-methylpyrazole-N-2)zinc(II)], [Zn-2(C6H8N3O)(2)(C2H3O2)(2)(C6H9N3O)(2)], exists as a centrosymmetric binuclear molecule with two tetrahedrally coordinated Zn atoms bridged by two pyrazolate anions. The geometry of the terminal and bridging pyrazole ligands are slightly different as a consequence of their differing modes of coordination

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Transition metal complexes with pyrazole-derived ligands. XI. [Zn(mu-L)(HL)(OAc)](2) (HL is 4-acetyl-3-amino-5-methylpyrazole)

Abstract

Extracted data

Transition metal complexes with pyrazole-derived ligands. XI. [Zn(mu-L)(HL)(OAc)](2) (HL is 4-acetyl-3-amino-5-methylpyrazole)

Abstract

Extracted data

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