Onsager's paper on phase transition and phase coexistence in anisotropic colloidal systems is a landmark in the theory of lyotropic liquid crystals. However, an uncompromising scrutiny of Onsager's original derivation reveals that it would be rigorously valid only for ludicrous values of the system's number density (of the order of the reciprocal of the number of particles). Based on Penrose's tree identity and an appropriate variant of the mean-field approach for purely repulsive, hard-core interactions, our theory shows that Onsager's theory is indeed valid for a reasonable range of densities
A fluid of hard right isosceles triangles was studied using an extension of scaled-particle density-...
Onsager-like theories are commonly used to describe the phase behavior of nematic (only orientationa...
Results are presented from a variety of molecular simulations of phase coexistence using the well es...
Onsager's paper on phase transition and phase coexistence in anisotropic colloidal systems is a land...
Parsons-Lee and Onsager theories are formulated for the isotropic-nematic transition in a binary mix...
The phase behavior and structure of a simple square-well bulk fluid with anisotropic interactions is...
A liquid crystal (LC) is a substance that exhibits phases intermediate between a crystal and a diso...
Since the work of Onsager, systems of hard spherocylinders have played a special role as the theoret...
Abstract The density-dependent distribution function of the orientation of the long axis of rod-like...
We show that the exact orientation distribution function (ODF) of the Onsager model for the nematic...
We have extended the Andrews method to derive the thermodynamic properties of an ensemble of spheroc...
The celebrated work of Onsager on hard particle systems, based on the truncated second order virial ...
Modifications to the traditional Onsager theory for modeling isotropic–nematic phase transitions in ...
7 pages, 8 figures.-- PACS nrs.: 64.70.Md, 61.30-v.A second-virial Onsager theory, based on Parsons-...
A formalism based on cluster expansion for non-uniform fluid is found useful for the discussion of v...
A fluid of hard right isosceles triangles was studied using an extension of scaled-particle density-...
Onsager-like theories are commonly used to describe the phase behavior of nematic (only orientationa...
Results are presented from a variety of molecular simulations of phase coexistence using the well es...
Onsager's paper on phase transition and phase coexistence in anisotropic colloidal systems is a land...
Parsons-Lee and Onsager theories are formulated for the isotropic-nematic transition in a binary mix...
The phase behavior and structure of a simple square-well bulk fluid with anisotropic interactions is...
A liquid crystal (LC) is a substance that exhibits phases intermediate between a crystal and a diso...
Since the work of Onsager, systems of hard spherocylinders have played a special role as the theoret...
Abstract The density-dependent distribution function of the orientation of the long axis of rod-like...
We show that the exact orientation distribution function (ODF) of the Onsager model for the nematic...
We have extended the Andrews method to derive the thermodynamic properties of an ensemble of spheroc...
The celebrated work of Onsager on hard particle systems, based on the truncated second order virial ...
Modifications to the traditional Onsager theory for modeling isotropic–nematic phase transitions in ...
7 pages, 8 figures.-- PACS nrs.: 64.70.Md, 61.30-v.A second-virial Onsager theory, based on Parsons-...
A formalism based on cluster expansion for non-uniform fluid is found useful for the discussion of v...
A fluid of hard right isosceles triangles was studied using an extension of scaled-particle density-...
Onsager-like theories are commonly used to describe the phase behavior of nematic (only orientationa...
Results are presented from a variety of molecular simulations of phase coexistence using the well es...