Matrix-assisted diffusion-ordered NMR spectroscopy with an invisible, tuneable matrix
- Hernandez-Cid, A.
- Piekarska, M.
- Adams, R.W.
- Nilsson, M.
- Evans, R.
- Morris, G.A.
Publication date
January 2017
DOI Publisher
Royal Society of Chemistry (RSC) Language
EnglishAbstract
Mixtures of species of similar sizes can be analysed with 1H NMR using diffusion-ordered spectroscopy (DOSY), by adding a co-solute with which different analytes interact to different extents (“matrix-assisted DOSY”). A matrix containing aqueous perfluorooctanoate micelles has the dual advantages of invisibility to 1H NMR, and interactions tuneable by adjusting the pH
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