In contrast to Se[CH2C(O)OH]2 versus S[CH2C(O)OH](2), the title compound, Se[CH(2)CH(2)C(O)OH]2 or C6H10O4Se, is structurally quite similar to its sulfur analogue. The molecule has twofold symmetry. The C-Se-C bond angle is 96.48 (8) degrees and the Se-C bond lengths are 1.9610 (14) Å. The shortest SeO intermolecular distance is 3.5410 (11) Å. The OO distances in the carboxylic acid dimers are 2.684 (2) Å. The temperature dependence of the IR spectrum suggests tautomerism in the solid state. Formula: C6H10O4S
The study includes the crystallographic analysis of interactions of S and Se from Cys, Met, Sec and ...
Numerous crystal structures are available for the dimeric amino acid cystine. In proteins it is form...
Sherpa Romeo green journalThe analysis of the title compound, C8H7N2OSe2, shows that its crystals a...
In contrast to Se[CH2C(O)OH]2 versus S[CH2C(O)OH](2), the title compound, Se[CH(2)CH(2)C(O)OH]2 or C...
Attempts to prepare [Se(CH2CH2COOH)3]+Cl− from Se(CH2CH2COOH)2 and H2C=CHCOOH in concentrated hydroc...
A new cause of molecular dissymmetry was discovered in 1934 by Lesslie and Turner who showed that 10...
Statistical analysis of data from crystal structures extracted from the Cambridge Structural Databas...
The controlled oxidation reaction of L-selenocystine under neutral pH conditions affords selenocyste...
TThe title compounds, X(CH2COOH)2(CH2COO), X = S, 1, and X = Se, 2, have been characterised by FTIR,...
R factor = 0.040; wR factor = 0.114; data-to-parameter ratio = 19.7. In the title compound, C21H18O2...
The historical survey traces the development of the electronic theory of valency; defines the polar,...
The two title compounds, C8H6O2S6 and C8H6O2S4Se2, are isotypic with very similar cell parameters. T...
The controlled oxidation reaction of L-selenocystine under neutral pH conditions affords selenocyste...
The novel selenocarboxylic Se-acids, HCF 2C(O)SeH and ClCF 2C(O)SeH, were prepared by treating the c...
R factor = 0.041; wR factor = 0.122; data-to-parameter ratio = 14.8. In the title molecule, C14H10O4...
The study includes the crystallographic analysis of interactions of S and Se from Cys, Met, Sec and ...
Numerous crystal structures are available for the dimeric amino acid cystine. In proteins it is form...
Sherpa Romeo green journalThe analysis of the title compound, C8H7N2OSe2, shows that its crystals a...
In contrast to Se[CH2C(O)OH]2 versus S[CH2C(O)OH](2), the title compound, Se[CH(2)CH(2)C(O)OH]2 or C...
Attempts to prepare [Se(CH2CH2COOH)3]+Cl− from Se(CH2CH2COOH)2 and H2C=CHCOOH in concentrated hydroc...
A new cause of molecular dissymmetry was discovered in 1934 by Lesslie and Turner who showed that 10...
Statistical analysis of data from crystal structures extracted from the Cambridge Structural Databas...
The controlled oxidation reaction of L-selenocystine under neutral pH conditions affords selenocyste...
TThe title compounds, X(CH2COOH)2(CH2COO), X = S, 1, and X = Se, 2, have been characterised by FTIR,...
R factor = 0.040; wR factor = 0.114; data-to-parameter ratio = 19.7. In the title compound, C21H18O2...
The historical survey traces the development of the electronic theory of valency; defines the polar,...
The two title compounds, C8H6O2S6 and C8H6O2S4Se2, are isotypic with very similar cell parameters. T...
The controlled oxidation reaction of L-selenocystine under neutral pH conditions affords selenocyste...
The novel selenocarboxylic Se-acids, HCF 2C(O)SeH and ClCF 2C(O)SeH, were prepared by treating the c...
R factor = 0.041; wR factor = 0.122; data-to-parameter ratio = 14.8. In the title molecule, C14H10O4...
The study includes the crystallographic analysis of interactions of S and Se from Cys, Met, Sec and ...
Numerous crystal structures are available for the dimeric amino acid cystine. In proteins it is form...
Sherpa Romeo green journalThe analysis of the title compound, C8H7N2OSe2, shows that its crystals a...