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Enantioselective Conjugate Addition of Nitroalkanes to Alkylidenemalonates Promoted by Thiourea-based Bifunctional Organocatalysts

  • CHIARUCCI, MICHEL
  • LOMBARDO, MARCO
  • TROMBINI, CLAUDIO
  • QUINTAVALLA, ARIANNA
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Publication date
January 2012
Icon DOI
10.1002/adsc.201100732
ISSN
1615-4150
Citation count (estimate)
15

Abstract

Cinchona alkaloids-derived bifunctional thioureas efficiently catalyse the enantioselective conjugate addition of nitroalkanes to alkylidenemalonates with syn-diastereopreference, opening a route to the synthesis of optically active ?-amino acid derivatives

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