none8Weatherable semicrystalline polyesters based on 1,4 cyclohexanedimethanol, 1,4-cyclohexanedicarboxylic acid (CHDA) or dimethyl 1,4-cyclohexane dicarboxylate (DMCD) can be prepared under normal melt-phase conditions, using titanium tetrabutoxide as catalyst.The effect of monomer ratio, reaction temperature and catalyst loading on the final polymer properties was studied. Under the proper polymerization conditions, poly(1,4 cyclohexylenedimethylene-1,4-cyclohexanedicarboxylate) polymers with high molecular weight can be obtained. During polymerization, isomerization can occur towards the thermodynamically stable cis-trans ratio of 34–66 mol%. Carboxylic acid end groups can catalyze the isomerization and therefore the polymerization is m...
Isohexides, like e.g. isosorbide, are well-known carbohydrate-based rigid diols which are capable of...
none4Nowadays the urgency for solving plastic waste problems is inducing academic and industrial res...
Isohexides, like e.g. isosorbide, are well-known carbohydrate-based rigid diols which are capable of...
Weatherable semicrystalline polyesters based on 1,4 cyclohexanedimethanol, 1,4-cyclohexanedicarboxyl...
Weatherable semicrystalline polyesters based on 1,4-cyclohexanedimethanol, 1,4-cyclohexanedicarboxyl...
Cyclic oligomers of poly(1,4-cyclohexylenedimethylene terephthalate) (PCT) were prepared by reaction...
Poly(cyclohexane-1,4-dimethylene cyclohexane-1,4-dicarboxylate) has been prepared by solid-state pol...
The synthetic problems associated with melt polymerizations to form homopolyesters of isosorbide (IS...
Poly(1,4-cyclohexanedicarboxylate)s, esp. poly(1,4-cyclohexanedimethylene-1,4-cyclohexanedicarboxyla...
Poly(1,4-cyclohexanedicarboxylate)s, esp. poly(1,4-cyclohexanedimethylene-1,4-cyclohexanedicarboxyla...
Aliphatic polyesters containing 1,4-cyclohexylene rings are an interesting class of materials, not y...
The synthetic problems associated with melt polymerizations to form homopolyesters of isosorbide (IS...
We report the synthesis and characterisation of an extended series of biodegradable cycloaliphatic p...
In this work, we report the synthesis of poly(ethylene furanoate) (PEF), catalyzed by three differen...
In the current manuscript, a new approach for the synthesis of poly(1,4- cyclohexanedimethylene 2,6-...
Isohexides, like e.g. isosorbide, are well-known carbohydrate-based rigid diols which are capable of...
none4Nowadays the urgency for solving plastic waste problems is inducing academic and industrial res...
Isohexides, like e.g. isosorbide, are well-known carbohydrate-based rigid diols which are capable of...
Weatherable semicrystalline polyesters based on 1,4 cyclohexanedimethanol, 1,4-cyclohexanedicarboxyl...
Weatherable semicrystalline polyesters based on 1,4-cyclohexanedimethanol, 1,4-cyclohexanedicarboxyl...
Cyclic oligomers of poly(1,4-cyclohexylenedimethylene terephthalate) (PCT) were prepared by reaction...
Poly(cyclohexane-1,4-dimethylene cyclohexane-1,4-dicarboxylate) has been prepared by solid-state pol...
The synthetic problems associated with melt polymerizations to form homopolyesters of isosorbide (IS...
Poly(1,4-cyclohexanedicarboxylate)s, esp. poly(1,4-cyclohexanedimethylene-1,4-cyclohexanedicarboxyla...
Poly(1,4-cyclohexanedicarboxylate)s, esp. poly(1,4-cyclohexanedimethylene-1,4-cyclohexanedicarboxyla...
Aliphatic polyesters containing 1,4-cyclohexylene rings are an interesting class of materials, not y...
The synthetic problems associated with melt polymerizations to form homopolyesters of isosorbide (IS...
We report the synthesis and characterisation of an extended series of biodegradable cycloaliphatic p...
In this work, we report the synthesis of poly(ethylene furanoate) (PEF), catalyzed by three differen...
In the current manuscript, a new approach for the synthesis of poly(1,4- cyclohexanedimethylene 2,6-...
Isohexides, like e.g. isosorbide, are well-known carbohydrate-based rigid diols which are capable of...
none4Nowadays the urgency for solving plastic waste problems is inducing academic and industrial res...
Isohexides, like e.g. isosorbide, are well-known carbohydrate-based rigid diols which are capable of...