Free energies, enthalpies, and entropies of formation of Ni(II), Cu(II), Zn(II), and proton complexes of H2N(CH2)2NH(CH2)3NH(CH2)2NH2 were detd. calorimetrically at 25°. The high stability of the metal complexes was due to the enthalpy term even when the entropy term was favorable
The stability constants of the 1:1 binary complexes of Ni(II) and Co(II) with 3-amino-1,2,4-triazole...
The title relation was obsd. for aq. CuL2+, where L is H2N(CH2)lNH(CH2)mNH(CH2)nNH2 (l, m, n = 2,2,2...
The problem of characterisation of species present at equilibrium in an electrolyte solution is disc...
The enthalpies of the reactions of the title tetraamines H2N(CH2)nNH(CH2)mNH(CH2)nNH2 (I) with H, Cu...
Heats of protonation and formation of Ni(II), Cu(II), and Zn(II) complexes of the quadridentate liga...
This work describes the accurate measurement of the thermodynamic functions Delta G degree and ...
The enthalpy and entropy of the reaction of H+ and Zn [7440-66-6] with 1,3,5-cis,cis-triaminocyclohe...
The enthalpies of the reactions between NH2(CH2)2NH(CH2)3NH2 and Ni2+, Cu2+, and Zn2+ in 0.5M KNO3 a...
The heats of formation of 1:1 and 1:2 complexes of Ni2+ and Cu2+ with the ligand 1,3,5-cis,cis-triam...
Linear relations were tested between heat of Cu2+ alkylamine chelate formation in aq. soln., ΔHaq, a...
The thermodynamic functions of formation of Cu(II) and Ni(II) complexes of some β-diketones, vi...
Equil. in 0.5M KNO3 at 25° between Cu(II) and the ligands (L) H2N(CH2)2NH2, MeNH(CH2)2NHMe, and Me2N...
Std. thermodynamic functions for the equil. [CuL2]2+ + X- .dblharw. [CuL2X]+ where L = en and H2N(CH...
Access to the enthalpy and entropy of the formation of metal complexes in solution is essential for ...
The enthalpies of formation of the title complexes were detd. in aq. soln. at 25° by a direct calori...
The stability constants of the 1:1 binary complexes of Ni(II) and Co(II) with 3-amino-1,2,4-triazole...
The title relation was obsd. for aq. CuL2+, where L is H2N(CH2)lNH(CH2)mNH(CH2)nNH2 (l, m, n = 2,2,2...
The problem of characterisation of species present at equilibrium in an electrolyte solution is disc...
The enthalpies of the reactions of the title tetraamines H2N(CH2)nNH(CH2)mNH(CH2)nNH2 (I) with H, Cu...
Heats of protonation and formation of Ni(II), Cu(II), and Zn(II) complexes of the quadridentate liga...
This work describes the accurate measurement of the thermodynamic functions Delta G degree and ...
The enthalpy and entropy of the reaction of H+ and Zn [7440-66-6] with 1,3,5-cis,cis-triaminocyclohe...
The enthalpies of the reactions between NH2(CH2)2NH(CH2)3NH2 and Ni2+, Cu2+, and Zn2+ in 0.5M KNO3 a...
The heats of formation of 1:1 and 1:2 complexes of Ni2+ and Cu2+ with the ligand 1,3,5-cis,cis-triam...
Linear relations were tested between heat of Cu2+ alkylamine chelate formation in aq. soln., ΔHaq, a...
The thermodynamic functions of formation of Cu(II) and Ni(II) complexes of some β-diketones, vi...
Equil. in 0.5M KNO3 at 25° between Cu(II) and the ligands (L) H2N(CH2)2NH2, MeNH(CH2)2NHMe, and Me2N...
Std. thermodynamic functions for the equil. [CuL2]2+ + X- .dblharw. [CuL2X]+ where L = en and H2N(CH...
Access to the enthalpy and entropy of the formation of metal complexes in solution is essential for ...
The enthalpies of formation of the title complexes were detd. in aq. soln. at 25° by a direct calori...
The stability constants of the 1:1 binary complexes of Ni(II) and Co(II) with 3-amino-1,2,4-triazole...
The title relation was obsd. for aq. CuL2+, where L is H2N(CH2)lNH(CH2)mNH(CH2)nNH2 (l, m, n = 2,2,2...
The problem of characterisation of species present at equilibrium in an electrolyte solution is disc...