Synthesis and Electrochemistry of New Rh-Centered and Conjuncto Rhodium Carbonyl Clusters. X-ray Structure of [NEt4]3[Rh15(CO)27], [NEt4]3[Rh15(CO)25(MeCN)2]•2MeCN, and , [NEt4]3[Rh17(CO)37]

Synthesis, structure, and spectroscopic characterization of Rh22 Rh13Cu(MeCN) clusters: assessment of CV and DPV as techniques to circumstantiate the presence of elusive hydride atoms

Collini D.
Dolzhnikov D. S.
Femoni C.
Iapalucci M. C.
Longoni G.
Tiozzo C.
Zacchini S.
FABRIZI DE BIANI, FABRIZIA
ZANELLO, PIERO

January 2011

The previously ill-characterized [HxRh22(CO)(35)](4-/5-) carbonyl cluster has been obtained as a byp...

Rh–Sb Nanoclusters: Synthesis, Structure, and Electrochemical Studies of the Atomically Precise [Rh20Sb3(CO)36]3– and [Rh21Sb2(CO)38]5– Carbonyl Compounds

Femoni, Cristina
Funaioli, Tiziana
Iapalucci, Maria Carmela
Ruggieri, Silvia
Zacchini, Stefano

January 2020

The reactivity of [Rh7(CO)16]3- with SbCl3 has been deeply investigated with the aim of finding a ne...

Synthesis, Structure, and Spectroscopic Characterization of [H8−nRh22(CO)35]n− (n = 4, 5) and [H2Rh13(CO)24{Cu(MeCN)}2]− Clusters: Assessment of CV and DPV As Techniques to Circumstantiate the Presence of Elusive Hydride Atoms

July 2015

none9The previously ill-characterized [HxRh22(CO)(35)](4-/5-) carbonyl cluster has been obtained as ...

Synthesis and Electrochemistry of new rh-centered and conjuncto rhodium carbonyl clusters. X-ray structure of [NEt4](3)[Rh-15(CO)(27)], [NEt4](3)[Rh-15(CO)(25)(MeCN)(2)]center dot 2MeCN, and [NEt4](3)[Rh-17(CO)(37)]

Collini, D.
Femoni, C.
Kaswalder, F.
Iapalucci, M. C.
Longoni, G.
Tiozzo, C.
Zacchini, S.
FABRIZI DE BIANI, FABRIZIA
FEDI, SERENA
ZANELLO, PIERO

January 2007

A reinvestigation of the redox chemistry of [Rh7(CO)16]3- resulted in the finding of new alternative...

Synthesis and characterization of new Rh- and Sn-centred and conjuncto rhodium carbonyl clusters

July 2015

none7noneC. Femoni; B. T. Heaton; M. C. Iapalucci; J. A. Iggo; G. Longoni; C. Tiozzo; S. ZacchiniC. ...

Synthesis and characterisation of new Rh- and Sn-centred and conjuncto rhodium carbonyl clusters

July 2015

none7noneC. Femoni; B. T. Heaton; M. C. Iapalucci; J. A. Iggo; G. Longoni; C. Tiozzo; S. ZacchiniC. ...

Synthesis and characterization of bew Rh- and Sn-centred and conjuncto rhodium carbonyl clusters

July 2015

none7noneC. Femoni; B. T. Heaton; M. C. Iapalucci; J. A. Iggo; G. Longoni; C. Tiozzo; S. ZacchiniC. ...

Redox Behaviour of Rh-centred [H3Rh13(CO)24]2-, [H4-nRh14(CO)25]n- and [H8-nRh22(CO)35]n- and Synthesis of the New [Rh15(CO)25(MeCN)2]3- and [Rh12(µ10-Sn)(CO)23Br2]4-Clusters

July 2015

none7noneD. Collini; F. Fabrizi De Biani; C. Femoni; M. C. Iapalucci; F. Kaswalder; G. Longoni; P. Z...

High nuclearity carbonyl clusters of rhodium. Synthesis and crystal structure of (NMe4)3[Rh14H(CO)25] \ub7 Me2CO

G. Ciani
M. Moret
A. Sironi
S. Martinengo

January 1989

The compound (NMe4)3[Rh14H(CO)25] \ub7 Me2CO has been obtained by treatment of (NMe4)4[Rh14(CO)25] w...

Synthesis, reactivity, electrochemical behavior, and crystal structure of a family of multivalent metal carbido-carbonyl clusters based on the Rh10(C)2Au4-6framework

Cherchi, Laura
Fumagalli, Alessandro
Fedi, Serena
Zanello, Piero
Fabrizi De Biani, Fabrizia
Laschi, Franco
Garlaschelli, Luigi
MacChi, Piero
Sironi, Angelo

January 2012

Six metal carbido-carbonyl clusters have been isolated and recognized as members of a multivalent fa...

SYNTHESIS OF 2 NOVEL PENTANUCLEAR RHODIUM CLUSTERS BEARING THE ALKYL-LIKE LIGANDS CH2COOME AND CH2CN - X-RAY STRUCTURE OF [PPH4]2[RH5(MU-CO)6(CO)8(CH2CN)]

F. RAGAINI
F. PORTA
A. FUMAGALLI
F. DEMARTIN

January 1991

The reaction of [PPh4][Rh(CO)4] (1) under CO with BrCH2COOMe or BrCH2CN in a 5:3 molar ratio gave hi...

A large rhodium carbonyl cluster compound containing four encapsulated nitrogen atoms: Synthesis and X-ray structure of the anion [Rh 23N4(CO)20(\u3bc-CO)18]3

S. Martinengo
G. Ciani
A. Sironi

January 1992

The novel anion [Rh23N4(CO)20(\u3bc-CO) 18]3-, obtained by controlled pyrolysis of [Rh 6N(CO)15]-, c...

A novel high-nuclearity rhodium carbonyl cluster compound containing two interstitial nitrogen atoms : Synthesis and X-ray structure of the anion [Rh 14N2(CO)25]2

S. Martinengo
G. Ciani
A. Sironi

January 1991

The novel anion [Rh14N2(CO)25] 2-, obtained by pyrolysis of [Rh6N(CO)15] -, contains a metal-centred...

Heterometallic Rhodium Clusters as Possible Nanocapacitors: Chemical, Electrochemical and Theoretical Studies of the Centred-Icosahedral [Rh12E(CO)27]n- Atomically-Precise Carbonyl Compounds

Cristiana Cesari
Cristina Femoni
Tiziana Funaioli
Maria Carmele Iapalucci
Ivan Rivalta
Silvia Ruggieri
Stefano Zacchini

January 2021

In this paper, we present a comparative study of the redox properties of the icosahedral [Rh12E(CO)2...

Synthesis, reactivity, electrochemical behavior, and crystal structure of a family of multivalent metal carbido–carbonyl clusters based on the Rh10(C)2Au4–6 framework

Cherchi, L.
Fumagalli, A.
Garlaschelli, L.
Macchi, P.
Sironi, A.
FEDI, SERENA
ZANELLO, PIERO
FABRIZI DE BIANI, FABRIZIA
LASCHI, FRANCO

January 2012

Six metal carbido−carbonyl clusters have been isolated and recognized as members of a multivalent fa...

Synthesis, structure, and spectroscopic characterization of Rh22 Rh13Cu(MeCN) clusters: assessment of CV and DPV as techniques to circumstantiate the presence of elusive hydride atoms

Collini D.
Dolzhnikov D. S.
Femoni C.
Iapalucci M. C.
Longoni G.
Tiozzo C.
Zacchini S.
FABRIZI DE BIANI, FABRIZIA
ZANELLO, PIERO

January 2011

The previously ill-characterized [HxRh22(CO)(35)](4-/5-) carbonyl cluster has been obtained as a byp...

Rh–Sb Nanoclusters: Synthesis, Structure, and Electrochemical Studies of the Atomically Precise [Rh20Sb3(CO)36]3– and [Rh21Sb2(CO)38]5– Carbonyl Compounds

Femoni, Cristina
Funaioli, Tiziana
Iapalucci, Maria Carmela
Ruggieri, Silvia
Zacchini, Stefano

January 2020

The reactivity of [Rh7(CO)16]3- with SbCl3 has been deeply investigated with the aim of finding a ne...

Synthesis, Structure, and Spectroscopic Characterization of [H8−nRh22(CO)35]n− (n = 4, 5) and [H2Rh13(CO)24{Cu(MeCN)}2]− Clusters: Assessment of CV and DPV As Techniques to Circumstantiate the Presence of Elusive Hydride Atoms

July 2015

none9The previously ill-characterized [HxRh22(CO)(35)](4-/5-) carbonyl cluster has been obtained as ...

Synthesis and Electrochemistry of new rh-centered and conjuncto rhodium carbonyl clusters. X-ray structure of [NEt4](3)[Rh-15(CO)(27)], [NEt4](3)[Rh-15(CO)(25)(MeCN)(2)]center dot 2MeCN, and [NEt4](3)[Rh-17(CO)(37)]

Collini, D.
Femoni, C.
Kaswalder, F.
Iapalucci, M. C.
Longoni, G.
Tiozzo, C.
Zacchini, S.
FABRIZI DE BIANI, FABRIZIA
FEDI, SERENA
ZANELLO, PIERO

January 2007

A reinvestigation of the redox chemistry of [Rh7(CO)16]3- resulted in the finding of new alternative...

Synthesis and characterization of new Rh- and Sn-centred and conjuncto rhodium carbonyl clusters

July 2015

none7noneC. Femoni; B. T. Heaton; M. C. Iapalucci; J. A. Iggo; G. Longoni; C. Tiozzo; S. ZacchiniC. ...

Synthesis and characterisation of new Rh- and Sn-centred and conjuncto rhodium carbonyl clusters

July 2015

none7noneC. Femoni; B. T. Heaton; M. C. Iapalucci; J. A. Iggo; G. Longoni; C. Tiozzo; S. ZacchiniC. ...

Synthesis and characterization of bew Rh- and Sn-centred and conjuncto rhodium carbonyl clusters

July 2015

none7noneC. Femoni; B. T. Heaton; M. C. Iapalucci; J. A. Iggo; G. Longoni; C. Tiozzo; S. ZacchiniC. ...

Redox Behaviour of Rh-centred [H3Rh13(CO)24]2-, [H4-nRh14(CO)25]n- and [H8-nRh22(CO)35]n- and Synthesis of the New [Rh15(CO)25(MeCN)2]3- and [Rh12(µ10-Sn)(CO)23Br2]4-Clusters

July 2015

none7noneD. Collini; F. Fabrizi De Biani; C. Femoni; M. C. Iapalucci; F. Kaswalder; G. Longoni; P. Z...

High nuclearity carbonyl clusters of rhodium. Synthesis and crystal structure of (NMe4)3[Rh14H(CO)25] \ub7 Me2CO

G. Ciani
M. Moret
A. Sironi
S. Martinengo

January 1989

The compound (NMe4)3[Rh14H(CO)25] \ub7 Me2CO has been obtained by treatment of (NMe4)4[Rh14(CO)25] w...

Synthesis, reactivity, electrochemical behavior, and crystal structure of a family of multivalent metal carbido-carbonyl clusters based on the Rh10(C)2Au4-6framework

Cherchi, Laura
Fumagalli, Alessandro
Fedi, Serena
Zanello, Piero
Fabrizi De Biani, Fabrizia
Laschi, Franco
Garlaschelli, Luigi
MacChi, Piero
Sironi, Angelo

January 2012

Six metal carbido-carbonyl clusters have been isolated and recognized as members of a multivalent fa...

SYNTHESIS OF 2 NOVEL PENTANUCLEAR RHODIUM CLUSTERS BEARING THE ALKYL-LIKE LIGANDS CH2COOME AND CH2CN - X-RAY STRUCTURE OF [PPH4]2[RH5(MU-CO)6(CO)8(CH2CN)]

F. RAGAINI
F. PORTA
A. FUMAGALLI
F. DEMARTIN

January 1991

The reaction of [PPh4][Rh(CO)4] (1) under CO with BrCH2COOMe or BrCH2CN in a 5:3 molar ratio gave hi...

A large rhodium carbonyl cluster compound containing four encapsulated nitrogen atoms: Synthesis and X-ray structure of the anion [Rh 23N4(CO)20(\u3bc-CO)18]3

S. Martinengo
G. Ciani
A. Sironi

January 1992

The novel anion [Rh23N4(CO)20(\u3bc-CO) 18]3-, obtained by controlled pyrolysis of [Rh 6N(CO)15]-, c...

A novel high-nuclearity rhodium carbonyl cluster compound containing two interstitial nitrogen atoms : Synthesis and X-ray structure of the anion [Rh 14N2(CO)25]2

S. Martinengo
G. Ciani
A. Sironi

January 1991

The novel anion [Rh14N2(CO)25] 2-, obtained by pyrolysis of [Rh6N(CO)15] -, contains a metal-centred...

Heterometallic Rhodium Clusters as Possible Nanocapacitors: Chemical, Electrochemical and Theoretical Studies of the Centred-Icosahedral [Rh12E(CO)27]n- Atomically-Precise Carbonyl Compounds

Cristiana Cesari
Cristina Femoni
Tiziana Funaioli
Maria Carmele Iapalucci
Ivan Rivalta
Silvia Ruggieri
Stefano Zacchini

January 2021

In this paper, we present a comparative study of the redox properties of the icosahedral [Rh12E(CO)2...

Synthesis, reactivity, electrochemical behavior, and crystal structure of a family of multivalent metal carbido–carbonyl clusters based on the Rh10(C)2Au4–6 framework

Cherchi, L.
Fumagalli, A.
Garlaschelli, L.
Macchi, P.
Sironi, A.
FEDI, SERENA
ZANELLO, PIERO
FABRIZI DE BIANI, FABRIZIA
LASCHI, FRANCO

January 2012

Six metal carbido−carbonyl clusters have been isolated and recognized as members of a multivalent fa...

Synthesis, structure, and spectroscopic characterization of Rh22 Rh13Cu(MeCN) clusters: assessment of CV and DPV as techniques to circumstantiate the presence of elusive hydride atoms

Collini D.
Dolzhnikov D. S.
Femoni C.
Iapalucci M. C.
Longoni G.
Tiozzo C.
Zacchini S.
FABRIZI DE BIANI, FABRIZIA
ZANELLO, PIERO

January 2011

The previously ill-characterized [HxRh22(CO)(35)](4-/5-) carbonyl cluster has been obtained as a byp...

Rh–Sb Nanoclusters: Synthesis, Structure, and Electrochemical Studies of the Atomically Precise [Rh20Sb3(CO)36]3– and [Rh21Sb2(CO)38]5– Carbonyl Compounds

Femoni, Cristina
Funaioli, Tiziana
Iapalucci, Maria Carmela
Ruggieri, Silvia
Zacchini, Stefano

January 2020

The reactivity of [Rh7(CO)16]3- with SbCl3 has been deeply investigated with the aim of finding a ne...

Synthesis, Structure, and Spectroscopic Characterization of [H8−nRh22(CO)35]n− (n = 4, 5) and [H2Rh13(CO)24{Cu(MeCN)}2]− Clusters: Assessment of CV and DPV As Techniques to Circumstantiate the Presence of Elusive Hydride Atoms

July 2015

none9The previously ill-characterized [HxRh22(CO)(35)](4-/5-) carbonyl cluster has been obtained as ...

Synthesis and Electrochemistry of New Rh-Centered and Conjuncto Rhodium Carbonyl Clusters. X-ray Structure of [NEt4]3[Rh15(CO)27], [NEt4]3[Rh15(CO)25(MeCN)2]•2MeCN, and , [NEt4]3[Rh17(CO)37]

Abstract

Extracted data

Synthesis and Electrochemistry of New Rh-Centered and Conjuncto Rhodium Carbonyl Clusters. X-ray Structure of [NEt4]3[Rh15(CO)27], [NEt4]3[Rh15(CO)25(MeCN)2]•2MeCN, and , [NEt4]3[Rh17(CO)37]

Abstract

Extracted data

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