[eng] An ab initio computational study has been performed in order to evaluate the associative versus dissociative mechanism in the formation of ternary complexes of copper(II) N-salicylidene-aminoacidato with 2-aminopyridine (or pyrimidine). In order to diminish the extent of the calculations involved, 3-hydroxypropenal (for N-salicylidene) and guanidine (for 2-aminopyridine or pyrimidine) moieties have been used. In both mechanisms, only one transition state is detected, which corresponds to the increase of the coordination number (5 to 6 and 4 to 5 in the associative and dissociative pathways, respectively). These calculated transition states represent the coordination of the guanidine moiety to the copper complex. Although theoretical r...
In this thesis, we studied the conformational stability of the salicylaldehyde-N,N-disubstituted sem...
Formation constants of ternary complexes of copper(II), L/D-histidine and, in turn, glycine, L-alani...
Abstract Binary and ternary complexes of copper(II) with L-glutamic acid (Glu) and diamines 1,3-diam...
In this work, the formation of ternary complexes with their respective formation constants in the sy...
This paper reports the observation of a reversible disassembly process for a previously reported oc...
The dissociation of [CuII(L)His]•2+ complexes [L = diethylenetriamine (dien) or 1,4,7-triazacyclonon...
In this work, the formation of ternary complexes with their respective formation constants in the sy...
Computer based analysis of the potentiometric data obtained at 37°C and l=0.15 M; (NaCIO4) for ...
The interaction of [CuL(H2O)](H2L = salicylideneglycine or salicylidene-α-alanine) with cytidin...
In this chapter, the influence of non-covalent interactions on the complexes formed by the various b...
[eng] Three Cu and one Co complexes of three pyridine-2,6-dicarboxylic acid derivatives were synthes...
© 2017 Wiley Periodicals, Inc. Hydration of the copper(II) bis-complexes with glycine, serine, lysin...
In this thesis, several copper guanidinoquinoline bischelate complexes were developed as structural ...
Theoretical studies on DNA-cleavage properties of [Cu(bba)(diimine)] <b>1</b>–<b>4</b> have been c...
The coordination between N-p-methylbenzyl-D-galactonoamidine, a putative transition state analogue o...
In this thesis, we studied the conformational stability of the salicylaldehyde-N,N-disubstituted sem...
Formation constants of ternary complexes of copper(II), L/D-histidine and, in turn, glycine, L-alani...
Abstract Binary and ternary complexes of copper(II) with L-glutamic acid (Glu) and diamines 1,3-diam...
In this work, the formation of ternary complexes with their respective formation constants in the sy...
This paper reports the observation of a reversible disassembly process for a previously reported oc...
The dissociation of [CuII(L)His]•2+ complexes [L = diethylenetriamine (dien) or 1,4,7-triazacyclonon...
In this work, the formation of ternary complexes with their respective formation constants in the sy...
Computer based analysis of the potentiometric data obtained at 37°C and l=0.15 M; (NaCIO4) for ...
The interaction of [CuL(H2O)](H2L = salicylideneglycine or salicylidene-α-alanine) with cytidin...
In this chapter, the influence of non-covalent interactions on the complexes formed by the various b...
[eng] Three Cu and one Co complexes of three pyridine-2,6-dicarboxylic acid derivatives were synthes...
© 2017 Wiley Periodicals, Inc. Hydration of the copper(II) bis-complexes with glycine, serine, lysin...
In this thesis, several copper guanidinoquinoline bischelate complexes were developed as structural ...
Theoretical studies on DNA-cleavage properties of [Cu(bba)(diimine)] <b>1</b>–<b>4</b> have been c...
The coordination between N-p-methylbenzyl-D-galactonoamidine, a putative transition state analogue o...
In this thesis, we studied the conformational stability of the salicylaldehyde-N,N-disubstituted sem...
Formation constants of ternary complexes of copper(II), L/D-histidine and, in turn, glycine, L-alani...
Abstract Binary and ternary complexes of copper(II) with L-glutamic acid (Glu) and diamines 1,3-diam...