The Electronic and Magnetic Effects of 3d Transition Metal Impurities in Semiconductors

The subject of this dissertation is concerned almost exclusively with soft x-ray spectroscopy of the 3d transition metals. These relatively common metals, owing to their widespread availability, are already used in all facets of technology. Stainless steel is largely chromium, iron, and nickel; copper wires transmit nearly all of our electricity; nickel is used in the making of margarine. Their wide range of electronic properties, strength, and usefulness in chemical reactions underpins their versatility to the point where they are used in essentially everything we manufacture. Key to this thesis is their ability to induce magnetism. If realized, spintronic technologies would harness the semiconducting electronic properties of a material, while also utilizing the induced magnetic properties to transport spin polarized charge. The ability to advance digital logic (0s and 1s) from its current state as on/off switches controlled solely via current, to the spintronic method of flipping spins to an up or down state, would have vast consequences for the computing world. Heat dissipation and cooling issues would largely vanish, and computing speed would show large improvements, while being non-volatile when power is lost. Succinctly put, the broad goal of my studies focused on how transition metal impurities doped into host semiconductors in small proportions can influence the host material's electronic and magnetic properties. This was accomplished primarily through modelling experimental spectra with theoretical calculations, and then extracting information through their agreement. In doing this, it is possible to determine fundamental quantitative properties of for each 3d ion, and how each ion situates itself within the host lattice. This information can then be linked back to known properties of the material in order to determine which 3d ions, host materials, and synthesis conditions show promise for spintronic or other related technologies. For the study concerning Bi2Te3 it was shown that the various transition metals Cr, Mn, Fe, Co, Ni, and Cu each integrate themselves into the host crystal in a particular fashion. Manganese atoms substitute cleanly into Bi sites; chromium atoms are not absorbed into the bulk, but only the surface; iron prefers a mixture of oxidation states; and for cobalt and nickel a mixture of configurations was found. Similarly, with host materials TiO2 and ZnO, DFT calculations predicted that the probability of substitution by a transition metal atom into a Zn or Ti site decreased in probability as the atomic number of the dopant metal atom increases, with a greater chance of metallic clustering in TiO2. Spectroscopic measurements, along with crystal field calculations confirmed these trends though modelling and direct comparison of calculation and experiment. This allowed us to extract real physical properties of the system, such as oxidation state, local symmetry, and effects d-orbital energies, via the calculation parameters. In the ferromagnetic compound NiFe2O4, the Fe atoms are responsible for the magnetism, but are in three different unique sites of various oxidation states and symmetries. By theoretically modelling x-ray magnetic circular dichroism experiments I have shown how these three sites can be readily distinguished, and how the interplay between their individual contributions to the magnetism are necessary to understand how the bulk magnetism arises. Furthermore, only through modelling the experimental XMCD with calculations can it be understood how aluminum alloying affects the overall magnetism. As more non-magnetic aluminum atoms replace magnetic iron atoms, the overall strength of the magnetism does not continuously decrease, but in fact begins to increase again at a certain point; this unexpected and unintuitive result can only be explained using the methodology described above. Structural changes in regular white TiO2 occur under a high pressure atmosphere that cause it to turn black, as a result of mid band gap states forming. I was able to adapt a generally hard x-ray technique (EXAFS) to the soft x-ray regime using the capabilities of the REIXS beamline at the Canadian Light Source to probe the change in interatomic distances between the white and black materials and observe the undergone structural changes. The shift in atomic distances were then compared to distorted structures of the nominal material and a distortion in the vicinity of an oxygen vacancy were able to solve the dilemma of the nature of the distortion. The Chelyabinsk meteorite had a thermomagnetic analysis performed on it to determine the various Curie temperatures of the magnetic materials contained in it, which consists of nickel and iron. Through comparisons with magnetic phase charts, we showed that the meteorite contains an iron-nickel alloy, which is quite common. But the breakthrough finding that had not been observed before was the discovery of an extremely pure form of iron, which hadn't ever been observed to occur naturally before