Synthesis and Comparative Anion Binding Profiles of Two Diacqua Eu(III) Complexes
- IMPERIO D
- GIOVENZANA G
- LAW G.-L. PARKER D
- WALTON
- J.W
Publication date
January 2010
DOI Publisher
Royal Society of Chemistry (RSC) ISSN
1477-9226 Citation count (estimate)
15Abstract
Two di-aqua Eu(III) complexes of heptadentate ligands are reported that show differing reactivity profiles towards various anions; a cationic complex with two azaxanthone moieties exhibits pronounced selectivity towards bicarbonate with an affinity constant, logK = 2.65 (295 K, 0.1 M NaCl)
Add to ORKG