High photoresponsivity in a GaAs film synthesized on glass using a pseudo-single-crystal Ge seed layer

Research to synthesize a high-quality GaAs film on an inexpensive substrate has been continuing for decades in the quest to develop a solar cell that achieves both high efficiency and low-cost. Here, we applied a large-grained Ge layer on glass, formed by Al-induced layer exchange, to an epitaxial template for a GaAs film. The GaAs film, grown epitaxially from the Ge seed layer at 520 °C, became a pseudosingle crystal (grain size > 100 μm) with high (111) orientation. Reflecting the large grain size, the internal quantum efficiency reached 70% under a bias voltage of 1.0 V. This value approaches that of a simultaneously formed GaAs film on a single-crystal Ge wafer and is the highest for a GaAs film synthesized on glass at a low temperature. The application of a Ge seed layer formed by layer exchange offers excellent potential to develop high-efficiency thin-film solar cells with III–V compound semiconductors based on low-cost glass substrates.This work was supported financially by the JSPS KAKENHI (No. 17H04918). The authors are grateful to Dr. Y. Tominaga (Hiroshima University) for helpful discussions and Professor N. Usami (Nagoya University) for assistance with the microwave photoconductivity decay measurement. Some experiments were conducted at the International Center for Young Scientists at NIMS and the Nanotechnology Platform at the University of Tsukuba