The combined use of a halogen bond (XB) donor with trimethylsilyl halide was found to be an efficient cocatalytic system for the direct dehydroxylative coupling reaction of alcohol with various nucleophiles, such as allyltrimethylsilane and trimethylcyanide, to give the corresponding adduct in moderate to excellent yields. Detailed control experiments and mechanistic studies revealed that the XB interaction was crucial for the reaction. The application of this coupling reaction is also described
Herein, we report new allylation reactions using ring-strained allylalkoxysiletanes. These reactions...
Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. ...
Herein, we report new allylation reactions using ring-strained allylalkoxysiletanes. These reactions...
The combined use of a halogen bond (XB) donor with trimethylsilyl halide was found to be an efficien...
The umpolung alkylation of silyl enol ethers with an iodonium(III) ylide proceeds under mild conditi...
The four-coordinate zinc compound ToMZnH (1, ToM = tris(4,4-dimethyl-2-oxazolinyl)phenylborate) cata...
Background: Alcohols are widely used, and sometimes renewable, reagents but the hydroxyl moiety is a...
An O–Si bond construction protocol employing abundantly available and inexpensive NaOH as the cataly...
PtCl<sub>2</sub>, AgOTf or Hg(CF<sub>3</sub>CO<sub>2</sub>)<sub>2</sub> (1 - 5 mol%) efficiently cat...
The use of Me3SiO(-)/Bu4N(+) as a general activator of organotrimethylsilanes for addition reactions...
Cross-dehydrogenative coupling (CDC) of hydrosilanes with hydroxyl groups, using alkali metal hexame...
Cross-dehydrogenative coupling (CDC) of hydrosilanes with hydroxyl groups, using alkali metal hexame...
Cross-dehydrogenative coupling (CDC) of hydrosilanes with hydroxyl groups, using alkali metal hexame...
PtCl2, AgOTf or Hg(CF3CO2)2 (1 - 5 mol%) efficiently catalyze the addition of allyldimethylchlorosil...
The synthesis of silsesquioxanes from chlorosilanes has been investigated in this thesis using the “...
Herein, we report new allylation reactions using ring-strained allylalkoxysiletanes. These reactions...
Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. ...
Herein, we report new allylation reactions using ring-strained allylalkoxysiletanes. These reactions...
The combined use of a halogen bond (XB) donor with trimethylsilyl halide was found to be an efficien...
The umpolung alkylation of silyl enol ethers with an iodonium(III) ylide proceeds under mild conditi...
The four-coordinate zinc compound ToMZnH (1, ToM = tris(4,4-dimethyl-2-oxazolinyl)phenylborate) cata...
Background: Alcohols are widely used, and sometimes renewable, reagents but the hydroxyl moiety is a...
An O–Si bond construction protocol employing abundantly available and inexpensive NaOH as the cataly...
PtCl<sub>2</sub>, AgOTf or Hg(CF<sub>3</sub>CO<sub>2</sub>)<sub>2</sub> (1 - 5 mol%) efficiently cat...
The use of Me3SiO(-)/Bu4N(+) as a general activator of organotrimethylsilanes for addition reactions...
Cross-dehydrogenative coupling (CDC) of hydrosilanes with hydroxyl groups, using alkali metal hexame...
Cross-dehydrogenative coupling (CDC) of hydrosilanes with hydroxyl groups, using alkali metal hexame...
Cross-dehydrogenative coupling (CDC) of hydrosilanes with hydroxyl groups, using alkali metal hexame...
PtCl2, AgOTf or Hg(CF3CO2)2 (1 - 5 mol%) efficiently catalyze the addition of allyldimethylchlorosil...
The synthesis of silsesquioxanes from chlorosilanes has been investigated in this thesis using the “...
Herein, we report new allylation reactions using ring-strained allylalkoxysiletanes. These reactions...
Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. ...
Herein, we report new allylation reactions using ring-strained allylalkoxysiletanes. These reactions...