Iridium catalyzed functionalization of amines with CO2 and hydrosilanes

Resumen del trabajo presentado al 2nd Trans Pyrenean Meeting in Catalysis (TraPCat), celebrado en Tarragona (España) del 18 al 19 de octubre de 2018.The catalytic reaction of secondary and/or primary amines with CO2 and silicon-hydrides as reductants has emerged as a promising technology that allows the selective formylation and/or methylation of N-H bonds. Moreover, some catalytic systems have promoted the selective formation of silylcarbamates or aminals. The research team I lead has contributed in the development of this chemistry, particularly in the case of iridium-catalyzed processes. This oral contribution summarizes our recent unpublished results showing the influence of the nature of the catalyst, the reductant and the reaction conditions on the performance and selectivity of the different catalytic processes that have been studied.Peer reviewe